Facile N-N coupling and copper (II) promoted cleavage of N,N′-linked N-methylbenzimidazole

Doo Hwan Jeong; Won Jin Park; Jong Hwa Jeong; David G. Churchill; Hyosun Lee

doi:10.1016/j.inoche.2008.06.025

Facile N-N coupling and copper (II) promoted cleavage of N,N′-linked N-methylbenzimidazole

Doo Hwan Jeong, Won Jin Park, Jong Hwa Jeong, David G. Churchill, Hyosun Lee

Research output: Contribution to journal › Article › peer-review

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Abstract

Together with the facile and high yielding formation of N,N′-linked NHC ligand, the complexation of N-methylbenzimidazole (1a), N-methylbenzimdiazolium chloride (4a) and N,N′-linked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl₂ give a dichloro-bridged binuclear copper(II) species (Ia), as characterized by IR spectroscopy and X-ray.

Original language	English
Pages (from-to)	1170-1173
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2008.06.025
State	Published - Oct 2008

Keywords

Benzimidazole
N,N′-linked NHC
N-alkylbenzimidazole
N-heterocyclic carbenes (NHCs)

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10.1016/j.inoche.2008.06.025

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title = "Facile N-N coupling and copper (II) promoted cleavage of N,N′-linked N-methylbenzimidazole",

abstract = "Together with the facile and high yielding formation of N,N′-linked NHC ligand, the complexation of N-methylbenzimidazole (1a), N-methylbenzimdiazolium chloride (4a) and N,N′-linked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl2 give a dichloro-bridged binuclear copper(II) species (Ia), as characterized by IR spectroscopy and X-ray.",

keywords = "Benzimidazole, N,N′-linked NHC, N-alkylbenzimidazole, N-heterocyclic carbenes (NHCs)",

author = "Jeong, {Doo Hwan} and Park, {Won Jin} and Jeong, {Jong Hwa} and Churchill, {David G.} and Hyosun Lee",

year = "2008",

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doi = "10.1016/j.inoche.2008.06.025",

language = "English",

volume = "11",

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T1 - Facile N-N coupling and copper (II) promoted cleavage of N,N′-linked N-methylbenzimidazole

AU - Jeong, Doo Hwan

AU - Park, Won Jin

AU - Jeong, Jong Hwa

AU - Churchill, David G.

AU - Lee, Hyosun

PY - 2008/10

Y1 - 2008/10

N2 - Together with the facile and high yielding formation of N,N′-linked NHC ligand, the complexation of N-methylbenzimidazole (1a), N-methylbenzimdiazolium chloride (4a) and N,N′-linked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl2 give a dichloro-bridged binuclear copper(II) species (Ia), as characterized by IR spectroscopy and X-ray.

AB - Together with the facile and high yielding formation of N,N′-linked NHC ligand, the complexation of N-methylbenzimidazole (1a), N-methylbenzimdiazolium chloride (4a) and N,N′-linked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl2 give a dichloro-bridged binuclear copper(II) species (Ia), as characterized by IR spectroscopy and X-ray.

KW - Benzimidazole

KW - N,N′-linked NHC

KW - N-alkylbenzimidazole

KW - N-heterocyclic carbenes (NHCs)

UR - http://www.scopus.com/inward/record.url?scp=53149147731&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2008.06.025

DO - 10.1016/j.inoche.2008.06.025

M3 - Article

AN - SCOPUS:53149147731

SN - 1387-7003

VL - 11

SP - 1170

EP - 1173

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Facile N-N coupling and copper (II) promoted cleavage of N,N′-linked N-methylbenzimidazole

Abstract

Keywords

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