Finite element simulation of ion transfer reactions at a single micro-liquid liquid interface supported on a thin polymer film

Jacques Josserand; Jacques Morandini; Hye Jin Lee; Rosaria Ferrigno; Hubert H. Girault

doi:10.1016/S0022-0728(99)00052-2

Finite element simulation of ion transfer reactions at a single micro-liquid liquid interface supported on a thin polymer film

Jacques Josserand, Jacques Morandini, Hye Jin Lee, Rosaria Ferrigno, Hubert H. Girault

Research output: Contribution to journal › Conference article › peer-review

38 Scopus citations

Abstract

The electrochemical response of an ion transfer reaction at a polarised micro liquid liquid interface has been studied by a finite element method. A new penalty method developed for this application has been first validated by comparison with experimental and analytical results obtained for a symmetric micro interface. Then, asymmetric geometries have been studied and the influence on the voltammetric response of parameters such as micro hole depth, interface position within the hole and diffusion coefficient ratio is investigated.

Original language	English
Pages (from-to)	42-52
Number of pages	11
Journal	Journal of Electroanalytical Chemistry
Volume	468
Issue number	1
DOIs	https://doi.org/10.1016/S0022-0728(99)00052-2
State	Published - 17 Jun 1999
Event	Proceedings of the 1998 International Symposium on New Trends in Electroanalytical Chemistry - Seoul, Korea, Republic of Duration: 10 Sep 1998 → 12 Sep 1998

Keywords

Cyclic voltammetry
Finite element
Ion transfer
ITIES
Simulation

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10.1016/S0022-0728(99)00052-2

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title = "Finite element simulation of ion transfer reactions at a single micro-liquid liquid interface supported on a thin polymer film",

abstract = "The electrochemical response of an ion transfer reaction at a polarised micro liquid liquid interface has been studied by a finite element method. A new penalty method developed for this application has been first validated by comparison with experimental and analytical results obtained for a symmetric micro interface. Then, asymmetric geometries have been studied and the influence on the voltammetric response of parameters such as micro hole depth, interface position within the hole and diffusion coefficient ratio is investigated.",

keywords = "Cyclic voltammetry, Finite element, Ion transfer, ITIES, Simulation",

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T1 - Finite element simulation of ion transfer reactions at a single micro-liquid liquid interface supported on a thin polymer film

AU - Josserand, Jacques

AU - Morandini, Jacques

AU - Lee, Hye Jin

AU - Ferrigno, Rosaria

AU - Girault, Hubert H.

PY - 1999/6/17

Y1 - 1999/6/17

N2 - The electrochemical response of an ion transfer reaction at a polarised micro liquid liquid interface has been studied by a finite element method. A new penalty method developed for this application has been first validated by comparison with experimental and analytical results obtained for a symmetric micro interface. Then, asymmetric geometries have been studied and the influence on the voltammetric response of parameters such as micro hole depth, interface position within the hole and diffusion coefficient ratio is investigated.

AB - The electrochemical response of an ion transfer reaction at a polarised micro liquid liquid interface has been studied by a finite element method. A new penalty method developed for this application has been first validated by comparison with experimental and analytical results obtained for a symmetric micro interface. Then, asymmetric geometries have been studied and the influence on the voltammetric response of parameters such as micro hole depth, interface position within the hole and diffusion coefficient ratio is investigated.

KW - Cyclic voltammetry

KW - Finite element

KW - Ion transfer

KW - ITIES

KW - Simulation

UR - http://www.scopus.com/inward/record.url?scp=0032638140&partnerID=8YFLogxK

U2 - 10.1016/S0022-0728(99)00052-2

DO - 10.1016/S0022-0728(99)00052-2

M3 - Conference article

AN - SCOPUS:0032638140

SN - 1572-6657

VL - 468

SP - 42

EP - 52

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 1

T2 - Proceedings of the 1998 International Symposium on New Trends in Electroanalytical Chemistry

Y2 - 10 September 1998 through 12 September 1998

ER -

Finite element simulation of ion transfer reactions at a single micro-liquid liquid interface supported on a thin polymer film

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Keywords

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