Green hydrogen production from thermoelectric condensation of ambient moist air

As the world transitions towards reducing carbon emissions, green hydrogen produced through solar-powered alkaline water electrolysis (AWE) presents a promising eco-friendly fuel option. In response to the challenges caused by global warming, including air moisture saturation leading to unbalanced rainfall, flooding, concern for freshwater depletion and the limited availability of water and energy sources in arid regions. The present study introduces a novel method of integrating thermoelectric water condenser (TEWC) and AWE for green hydrogen production in remote and arid regions where both the water and the conventional energy sources are scarce. Numerical simulations of the present study show that the impact of relative humidity, temperature, and air flow rate significantly affect water condensation, energy requirement, and hydrogen production. The TEWC and AWE models showed excellent agreement with the experimental data. TEWC model reveled that the highest water production rate of 1.50 kg/(m²h) is achieved at ambient air temperature of 308 K and relative humidity of 80%. Furthermore, increasing the moist air flow from 1 m/s to 2 m/s results in a 47.5% increase in water production rate. The AWE model showed that cell's performance improved with higher temperatures, lower electrode-separator gap, and overpotentials. The hydrogen evolution rate reached a maximum of 5.2 kg/(m²h) at current density of 1.4 A/cm² and potential of 3.96 V. By optimizing the TEWC and AWE systems the integrated method proved to be an efficient way of converting moist air into green hydrogen using solar energy, making it a viable and sustainable setup in remote arid regions.