Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi; K. A. Udachin; K. Shin; S. Alavi; I. L. Moudrakovski; R. Ohmura; J. A. Ripmeester

doi:10.1039/c4cc02111h

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, R. Ohmura, J. A. Ripmeester

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Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO₂ molecules, which is found to provide high CO₂ storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Original language	English
Pages (from-to)	11476-11479
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	78
DOIs	https://doi.org/10.1039/c4cc02111h
State	Published - 4 Sep 2014

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title = "Guest-induced symmetry lowering of an ionic clathrate material for carbon capture",

abstract = "We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.",

author = "S. Muromachi and Udachin, {K. A.} and K. Shin and S. Alavi and Moudrakovski, {I. L.} and R. Ohmura and Ripmeester, {J. A.}",

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AU - Muromachi, S.

AU - Udachin, K. A.

AU - Shin, K.

AU - Alavi, S.

AU - Moudrakovski, I. L.

AU - Ohmura, R.

AU - Ripmeester, J. A.

PY - 2014/9/4

Y1 - 2014/9/4

N2 - We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

AB - We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

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U2 - 10.1039/c4cc02111h

DO - 10.1039/c4cc02111h

M3 - Article

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SN - 1359-7345

VL - 50

SP - 11476

EP - 11479

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

Abstract

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