High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy

Véronique Le Floc'h; Sophie Brasselet; Joseph Zyss; Bong Rae Cho; Sang Hae Lee; Seung Joon Jeon; Minhaeng Cho; Kil Sik Min; Myunghyun Paik Suh

doi:10.1002/adma.200400451

High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy

Véronique Le Floc'h
, Sophie Brasselet
, Joseph Zyss
, Bong Rae Cho
, Sang Hae Lee
, Seung Joon Jeon
, Minhaeng Cho
, Kil Sik Min
, Myunghyun Paik Suh

Department of Chemical Science Education

Ecl. Normale Sup. de Cachan
Korea University
Seoul National University

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

The high efficiency and quadratic nonlinear optical properties of 2D octupolar crystal of 1,3,5-tricyano-2,4,6-tris(p-diethylaminostyryl)benzene (TTB), which is characterized by nonlinear microscopy, was analyzed. The TTB single crystals were obtained by evaporating a saturated solution of TTB in CH₂Cl₂-EtOEt. To confirm optically the octupolar crystalline structure and determine the molecular arrangement inside the submillimeter-sized crystal, a polarized nonlinear microscopy technique was applied along with second harmonic generation (SHG) and two-photon fluorescence (TPF). The results show that optical polarization measurements of both SHG and TPF confirmed the non-centrosynmmetric threefold symmetry of the TTB crystal.

Original language	English
Pages (from-to)	196-200
Number of pages	5
Journal	Advanced Materials
Volume	17
Issue number	2
DOIs	https://doi.org/10.1002/adma.200400451
State	Published - 31 Jan 2005

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title = "High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy",

abstract = "The high efficiency and quadratic nonlinear optical properties of 2D octupolar crystal of 1,3,5-tricyano-2,4,6-tris(p-diethylaminostyryl)benzene (TTB), which is characterized by nonlinear microscopy, was analyzed. The TTB single crystals were obtained by evaporating a saturated solution of TTB in CH2Cl2-EtOEt. To confirm optically the octupolar crystalline structure and determine the molecular arrangement inside the submillimeter-sized crystal, a polarized nonlinear microscopy technique was applied along with second harmonic generation (SHG) and two-photon fluorescence (TPF). The results show that optical polarization measurements of both SHG and TPF confirmed the non-centrosynmmetric threefold symmetry of the TTB crystal.",

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year = "2005",

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day = "31",

doi = "10.1002/adma.200400451",

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volume = "17",

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journal = "Advanced Materials",

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T1 - High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy

AU - Le Floc'h, Véronique

AU - Brasselet, Sophie

AU - Zyss, Joseph

AU - Cho, Bong Rae

AU - Lee, Sang Hae

AU - Jeon, Seung Joon

AU - Cho, Minhaeng

AU - Min, Kil Sik

AU - Suh, Myunghyun Paik

PY - 2005/1/31

Y1 - 2005/1/31

N2 - The high efficiency and quadratic nonlinear optical properties of 2D octupolar crystal of 1,3,5-tricyano-2,4,6-tris(p-diethylaminostyryl)benzene (TTB), which is characterized by nonlinear microscopy, was analyzed. The TTB single crystals were obtained by evaporating a saturated solution of TTB in CH2Cl2-EtOEt. To confirm optically the octupolar crystalline structure and determine the molecular arrangement inside the submillimeter-sized crystal, a polarized nonlinear microscopy technique was applied along with second harmonic generation (SHG) and two-photon fluorescence (TPF). The results show that optical polarization measurements of both SHG and TPF confirmed the non-centrosynmmetric threefold symmetry of the TTB crystal.

AB - The high efficiency and quadratic nonlinear optical properties of 2D octupolar crystal of 1,3,5-tricyano-2,4,6-tris(p-diethylaminostyryl)benzene (TTB), which is characterized by nonlinear microscopy, was analyzed. The TTB single crystals were obtained by evaporating a saturated solution of TTB in CH2Cl2-EtOEt. To confirm optically the octupolar crystalline structure and determine the molecular arrangement inside the submillimeter-sized crystal, a polarized nonlinear microscopy technique was applied along with second harmonic generation (SHG) and two-photon fluorescence (TPF). The results show that optical polarization measurements of both SHG and TPF confirmed the non-centrosynmmetric threefold symmetry of the TTB crystal.

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U2 - 10.1002/adma.200400451

DO - 10.1002/adma.200400451

M3 - Article

AN - SCOPUS:13844280996

SN - 0935-9648

VL - 17

SP - 196

EP - 200

JO - Advanced Materials

JF - Advanced Materials

IS - 2

ER -

High efficiency and quadratic nonlinear optical properties of a fully optimized 2D octupolar crystal characterized by nonlinear microscopy

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