High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101

Philip L. Llewellyn, Sandrine Bourrelly, Christian Serre, Alexandre Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong San Chang, Do Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Férey

Research output: Contribution to journalArticlepeer-review

1097 Scopus citations

Abstract

Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g-1 or 390 cm3STp cm-3 at 5 MPa and 303 K.

Original languageEnglish
Pages (from-to)7245-7250
Number of pages6
JournalLangmuir
Volume24
Issue number14
DOIs
StatePublished - 15 Jul 2008

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