Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101

Michel Latroche, Suzy Surblé, Christian Serre, Caroline Mellot-Draznieks, Philip L. Llewellyn, Jin Ho Lee, Jong San Chang, Hwa Jhung Sung, Gérard Férey

Research output: Contribution to journalArticlepeer-review

750 Scopus citations

Abstract

Large hydrogen-storage capacity at liquid-nitrogen temperature is exhibited by the metal-organic framework MIL-101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene-1,4-dicarboxylate ligands. (Figure Presented).

Original languageEnglish
Pages (from-to)8227-8231
Number of pages5
JournalAngewandte Chemie - International Edition
Volume45
Issue number48
DOIs
StatePublished - 11 Dec 2006

Keywords

  • Carboxylate ligands
  • Chromium
  • Hydrogen
  • Mesoporous materials
  • Physisorption

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