Abstract
Large hydrogen-storage capacity at liquid-nitrogen temperature is exhibited by the metal-organic framework MIL-101. In the zeotype architecture of this porous solid (see picture) each intersection of the cages is occupied by a supertetrahedron formed by trimers of chromium octahedra assembled with benzene-1,4-dicarboxylate ligands. (Figure Presented).
Original language | English |
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Pages (from-to) | 8227-8231 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 45 |
Issue number | 48 |
DOIs | |
State | Published - 11 Dec 2006 |
Keywords
- Carboxylate ligands
- Chromium
- Hydrogen
- Mesoporous materials
- Physisorption