Increased power conversion efficiency of dye-sensitized solar cells with surface-modified photoelectrode

Ju Hee Oh, Giseop Kwak, Kang Bae, Myung Gyu Choi, Chang Hyun Lee, Hwa Min Kim, Yoon Soo Han

Research output: Contribution to journalArticlepeer-review

Abstract

A nanoporous TiO2 film was modified with an aqueous potassium chloride (KCl), and the resulting film was applied to the photoelectrode of dye-sensitizes solar cell (DSSC). The DSSC with KCl-modified photoelctrode showed an increase in short circuit current (Jsc) and open circuit voltage (Voc), resulting in a power conversion efficiency (PCE) of 7.04%, compared to that (6.36%) of reference device with bare TiO2. The suppression of charge recombination between photo-injected electrons and triiodide (I3-) ions was found to increase both Jsc and Voc of the device with KCl-modified photoelctrode.

Original languageEnglish
Pages (from-to)171-178
Number of pages8
JournalMolecular Crystals and Liquid Crystals
Volume617
Issue number1
DOIs
StatePublished - 13 Aug 2015

Keywords

  • dye-sensitized solar cell
  • photoelectrode
  • potassium chloride
  • recombination

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