Influence of trivalent praseodymium ion on SiO2–B2O3–Al2O3– BaO–CaO–Sb2O3–Na2O–Pr2O3 glasses for X-Rays shielding and luminescence materials

S. Kaewjaeng; W. Boonpa; F. Khrongchaiyaphum; S. Kothan; H. J. Kim; N. Intachai; R. Rajaramakrishna; S. Kiatwattanacharoen; J. Kaewkhao

doi:10.1016/j.radphyschem.2021.109467

Influence of trivalent praseodymium ion on SiO₂–B₂O₃–Al₂O₃– BaO–CaO–Sb₂O₃–Na₂O–Pr₂O₃ glasses for X-Rays shielding and luminescence materials

S. Kaewjaeng, W. Boonpa, F. Khrongchaiyaphum, S. Kothan, H. J. Kim, N. Intachai, R. Rajaramakrishna, S. Kiatwattanacharoen, J. Kaewkhao

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11 Scopus citations

Abstract

The work focuses on developing new alternative radiation shielding and visible luminescent glasses from (55-x) SiO₂: 13B₂O₃: 1Al₂O₃: 4.5BaO: 6.3CaO: 0.2Sb₂O_3: 20Na₂O:xPr₂O₃ where x = 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 mol% composition. Glasses have been fabricated by melt-quenching technique. Four emission bands at 484 nm, 528 nm, 605 nm, and 645 nm were observed. Highest emission intensity is observed for 1.0mol% of Pr³⁺ ions whereas radiation shielding ability showed better results for higher concentration of Pr³⁺ ions. Prominent blue emission around 482 nm is been strong in the present glasses. The radiation shielding properties have been evaluated and results show that all glass samples are better radiation shielding properties than ordinary concrete, red brick, and commercial windows.

Original language	English
Article number	109467
Journal	Radiation Physics and Chemistry
Volume	184
DOIs	https://doi.org/10.1016/j.radphyschem.2021.109467
State	Published - Jul 2021

Keywords

Luminescence
Praseodymium
Radiation
Shielding
X-ray

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Kaewjaeng, S., Boonpa, W., Khrongchaiyaphum, F., Kothan, S., Kim, H. J., Intachai, N., Rajaramakrishna, R., Kiatwattanacharoen, S., & Kaewkhao, J. (2021). Influence of trivalent praseodymium ion on SiO₂–B₂O₃–Al₂O₃– BaO–CaO–Sb₂O₃–Na₂O–Pr₂O₃ glasses for X-Rays shielding and luminescence materials. Radiation Physics and Chemistry, 184, Article 109467. https://doi.org/10.1016/j.radphyschem.2021.109467

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title = "Influence of trivalent praseodymium ion on SiO2–B2O3–Al2O3– BaO–CaO–Sb2O3–Na2O–Pr2O3 glasses for X-Rays shielding and luminescence materials",

abstract = "The work focuses on developing new alternative radiation shielding and visible luminescent glasses from (55-x) SiO2: 13B2O3: 1Al2O3: 4.5BaO: 6.3CaO: 0.2Sb2O3: 20Na2O:xPr2O3 where x = 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 mol% composition. Glasses have been fabricated by melt-quenching technique. Four emission bands at 484 nm, 528 nm, 605 nm, and 645 nm were observed. Highest emission intensity is observed for 1.0mol% of Pr3+ ions whereas radiation shielding ability showed better results for higher concentration of Pr3+ ions. Prominent blue emission around 482 nm is been strong in the present glasses. The radiation shielding properties have been evaluated and results show that all glass samples are better radiation shielding properties than ordinary concrete, red brick, and commercial windows.",

keywords = "Luminescence, Praseodymium, Radiation, Shielding, X-ray",

author = "S. Kaewjaeng and W. Boonpa and F. Khrongchaiyaphum and S. Kothan and Kim, {H. J.} and N. Intachai and R. Rajaramakrishna and S. Kiatwattanacharoen and J. Kaewkhao",

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year = "2021",

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doi = "10.1016/j.radphyschem.2021.109467",

language = "English",

volume = "184",

journal = "Radiation Physics and Chemistry",

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Kaewjaeng, S, Boonpa, W, Khrongchaiyaphum, F, Kothan, S, Kim, HJ, Intachai, N, Rajaramakrishna, R, Kiatwattanacharoen, S & Kaewkhao, J 2021, 'Influence of trivalent praseodymium ion on SiO₂–B₂O₃–Al₂O₃– BaO–CaO–Sb₂O₃–Na₂O–Pr₂O₃ glasses for X-Rays shielding and luminescence materials', Radiation Physics and Chemistry, vol. 184, 109467. https://doi.org/10.1016/j.radphyschem.2021.109467

TY - JOUR

T1 - Influence of trivalent praseodymium ion on SiO2–B2O3–Al2O3– BaO–CaO–Sb2O3–Na2O–Pr2O3 glasses for X-Rays shielding and luminescence materials

AU - Kaewjaeng, S.

AU - Boonpa, W.

AU - Khrongchaiyaphum, F.

AU - Kothan, S.

AU - Kim, H. J.

AU - Intachai, N.

AU - Rajaramakrishna, R.

AU - Kiatwattanacharoen, S.

AU - Kaewkhao, J.

PY - 2021/7

Y1 - 2021/7

N2 - The work focuses on developing new alternative radiation shielding and visible luminescent glasses from (55-x) SiO2: 13B2O3: 1Al2O3: 4.5BaO: 6.3CaO: 0.2Sb2O3: 20Na2O:xPr2O3 where x = 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 mol% composition. Glasses have been fabricated by melt-quenching technique. Four emission bands at 484 nm, 528 nm, 605 nm, and 645 nm were observed. Highest emission intensity is observed for 1.0mol% of Pr3+ ions whereas radiation shielding ability showed better results for higher concentration of Pr3+ ions. Prominent blue emission around 482 nm is been strong in the present glasses. The radiation shielding properties have been evaluated and results show that all glass samples are better radiation shielding properties than ordinary concrete, red brick, and commercial windows.

AB - The work focuses on developing new alternative radiation shielding and visible luminescent glasses from (55-x) SiO2: 13B2O3: 1Al2O3: 4.5BaO: 6.3CaO: 0.2Sb2O3: 20Na2O:xPr2O3 where x = 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 mol% composition. Glasses have been fabricated by melt-quenching technique. Four emission bands at 484 nm, 528 nm, 605 nm, and 645 nm were observed. Highest emission intensity is observed for 1.0mol% of Pr3+ ions whereas radiation shielding ability showed better results for higher concentration of Pr3+ ions. Prominent blue emission around 482 nm is been strong in the present glasses. The radiation shielding properties have been evaluated and results show that all glass samples are better radiation shielding properties than ordinary concrete, red brick, and commercial windows.

KW - Luminescence

KW - Praseodymium

KW - Radiation

KW - Shielding

KW - X-ray

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U2 - 10.1016/j.radphyschem.2021.109467

DO - 10.1016/j.radphyschem.2021.109467

M3 - Article

AN - SCOPUS:85103644480

SN - 0969-806X

VL - 184

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

M1 - 109467

ER -

Influence of trivalent praseodymium ion on SiO₂–B₂O₃–Al₂O₃– BaO–CaO–Sb₂O₃–Na₂O–Pr₂O₃ glasses for X-Rays shielding and luminescence materials

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Keywords

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