Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties

Rizhen Jin; Chan Sik Cho; Li Hong Jiang; Sang Chul Shim

doi:10.1016/S1381-1169(96)00368-8

Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties

Rizhen Jin, Chan Sik Cho, Li Hong Jiang, Sang Chul Shim

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The monomeric mono(iodosylbenzene) (tetraphenylporphinato)manganese(IV) derivatives, LMn(IV)TPP(OIPh) (2a and 2b) (L = 4-MeOC₆H₄O^- and 4-t-BuC₆H₄O^-) have been synthesized from the reaction of the corresponding (tetraphenylporphinato)manganese(III) derivatives 1a and 1b, LMn(III)TPP with iodosylbenzene, respectively. The complexes 2a and 2b have been characterized by elemental analyses, visible, infrared and ESR spectroscopy. These complexes are capable of oxidizing cyclohexane and styrene to give oxidation products in high yields at room temperature.

Original language	English
Pages (from-to)	343-347
Number of pages	5
Journal	Journal of Molecular Catalysis A: Chemical
Volume	116
Issue number	3
DOIs	https://doi.org/10.1016/S1381-1169(96)00368-8
State	Published - 7 Mar 1997

Keywords

Iodosylbenzene
Manganese
Oxidation
Tetraphenylporphyrin

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Jin, R., Cho, C. S., Jiang, L. H., & Shim, S. C. (1997). Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties. Journal of Molecular Catalysis A: Chemical, 116(3), 343-347. https://doi.org/10.1016/S1381-1169(96)00368-8

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title = "Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties",

abstract = "The monomeric mono(iodosylbenzene) (tetraphenylporphinato)manganese(IV) derivatives, LMn(IV)TPP(OIPh) (2a and 2b) (L = 4-MeOC6H4O- and 4-t-BuC6H4O-) have been synthesized from the reaction of the corresponding (tetraphenylporphinato)manganese(III) derivatives 1a and 1b, LMn(III)TPP with iodosylbenzene, respectively. The complexes 2a and 2b have been characterized by elemental analyses, visible, infrared and ESR spectroscopy. These complexes are capable of oxidizing cyclohexane and styrene to give oxidation products in high yields at room temperature.",

keywords = "Iodosylbenzene, Manganese, Oxidation, Tetraphenylporphyrin",

author = "Rizhen Jin and Cho, {Chan Sik} and Jiang, {Li Hong} and Shim, {Sang Chul}",

year = "1997",

month = mar,

day = "7",

doi = "10.1016/S1381-1169(96)00368-8",

language = "English",

volume = "116",

pages = "343--347",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

number = "3",

}

Jin, R, Cho, CS, Jiang, LH & Shim, SC 1997, 'Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties', Journal of Molecular Catalysis A: Chemical, vol. 116, no. 3, pp. 343-347. https://doi.org/10.1016/S1381-1169(96)00368-8

Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties. / Jin, Rizhen; Cho, Chan Sik; Jiang, Li Hong et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 116, No. 3, 07.03.1997, p. 343-347.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties

AU - Jin, Rizhen

AU - Cho, Chan Sik

AU - Jiang, Li Hong

AU - Shim, Sang Chul

PY - 1997/3/7

Y1 - 1997/3/7

N2 - The monomeric mono(iodosylbenzene) (tetraphenylporphinato)manganese(IV) derivatives, LMn(IV)TPP(OIPh) (2a and 2b) (L = 4-MeOC6H4O- and 4-t-BuC6H4O-) have been synthesized from the reaction of the corresponding (tetraphenylporphinato)manganese(III) derivatives 1a and 1b, LMn(III)TPP with iodosylbenzene, respectively. The complexes 2a and 2b have been characterized by elemental analyses, visible, infrared and ESR spectroscopy. These complexes are capable of oxidizing cyclohexane and styrene to give oxidation products in high yields at room temperature.

AB - The monomeric mono(iodosylbenzene) (tetraphenylporphinato)manganese(IV) derivatives, LMn(IV)TPP(OIPh) (2a and 2b) (L = 4-MeOC6H4O- and 4-t-BuC6H4O-) have been synthesized from the reaction of the corresponding (tetraphenylporphinato)manganese(III) derivatives 1a and 1b, LMn(III)TPP with iodosylbenzene, respectively. The complexes 2a and 2b have been characterized by elemental analyses, visible, infrared and ESR spectroscopy. These complexes are capable of oxidizing cyclohexane and styrene to give oxidation products in high yields at room temperature.

KW - Iodosylbenzene

KW - Manganese

KW - Oxidation

KW - Tetraphenylporphyrin

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U2 - 10.1016/S1381-1169(96)00368-8

DO - 10.1016/S1381-1169(96)00368-8

M3 - Article

AN - SCOPUS:0342275206

SN - 1381-1169

VL - 116

SP - 343

EP - 347

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 3

ER -

Isolation and characterization of monomeric mono(iodosylbenzene) manganese(IV) tetraphenylporphyrin complexes from the (tetraphenylporphinato) manganese(III) derivatives-iodosylbenzene systems and their oxidation properties

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