Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- And D2O-based electrolytes over palladium

Ji Hoon Lee; Brian M. Tackett; Zhenhua Xie; Sooyeon Hwang; Jingguang G. Chen

doi:10.1039/c9cc07611e

Isotopic effect on electrochemical CO₂ reduction activity and selectivity in H₂O- And D₂O-based electrolytes over palladium

Ji Hoon Lee, Brian M. Tackett, Zhenhua Xie, Sooyeon Hwang, Jingguang G. Chen

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The isotopic effect on the electrochemical CO₂ reduction reaction (CO₂RR) is investigated in this study. A higher CO₂RR selectivity over its competing hydrogen evolution reaction was observed in D₂O-based electrolytes compared with the H₂O-based counterparts, which can be attributed to the lower [D⁺] concentration than [H⁺].

Original language	English
Pages (from-to)	106-108
Number of pages	3
Journal	Chemical Communications
Volume	56
Issue number	1
DOIs	https://doi.org/10.1039/c9cc07611e
State	Published - 2019

Access to Document

10.1039/c9cc07611e

Cite this

@article{ff48e458e24844f0b415b1f38a9d9ff8,

title = "Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- And D2O-based electrolytes over palladium",

abstract = "The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. A higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+].",

author = "Lee, {Ji Hoon} and Tackett, {Brian M.} and Zhenhua Xie and Sooyeon Hwang and Chen, {Jingguang G.}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc07611e",

language = "English",

volume = "56",

pages = "106--108",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- And D2O-based electrolytes over palladium

AU - Lee, Ji Hoon

AU - Tackett, Brian M.

AU - Xie, Zhenhua

AU - Hwang, Sooyeon

AU - Chen, Jingguang G.

PY - 2019

Y1 - 2019

N2 - The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. A higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+].

AB - The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. A higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+].

UR - http://www.scopus.com/inward/record.url?scp=85076686426&partnerID=8YFLogxK

U2 - 10.1039/c9cc07611e

DO - 10.1039/c9cc07611e

M3 - Article

C2 - 31793562

AN - SCOPUS:85076686426

SN - 1359-7345

VL - 56

SP - 106

EP - 108

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Isotopic effect on electrochemical CO₂ reduction activity and selectivity in H₂O- And D₂O-based electrolytes over palladium

Abstract

Access to Document

Other files and links

Fingerprint

Cite this