Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins

Tomohiro Higashino; Jong Min Lim; Takahiro Miura; Shohei Saito; Jae Yoon Shin; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.201001765

Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins

Tomohiro Higashino, Jong Min Lim, Takahiro Miura, Shohei Saito, Jae Yoon Shin, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

Aromaticity with a twist: The reversal of Möbius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Möbius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Möbius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)

Original language	English
Pages (from-to)	4950-4954
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	29
DOIs	https://doi.org/10.1002/anie.201001765
State	Published - 5 Jul 2010

Keywords

Aromaticity
Hexaphyrins
Möbius aromaticity
Phosphorus
Porphyrinoids

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10.1002/anie.201001765

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abstract = "Aromaticity with a twist: The reversal of M{\"o}bius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π M{\"o}bius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized M{\"o}bius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)",

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AU - Higashino, Tomohiro

AU - Lim, Jong Min

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AU - Shin, Jae Yoon

AU - Kim, Dongho

AU - Osuka, Atsuhiro

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AB - Aromaticity with a twist: The reversal of Möbius aromaticity occurs by changing the number of π electrons between [4n + 2] and [4n] in monophosphorus complexes of [28]hexaphyrins and bisphosphorus complexes of [30]hexaphyrins. The 30π Möbius antiaromatic bisphosporus[30]hexaphyrins (see picture) were determined to be the first structurally characterized Möbius antiaromatic systems, which are rigid, neutral, and stable. (Figure Presented)

KW - Aromaticity

KW - Hexaphyrins

KW - Möbius aromaticity

KW - Phosphorus

KW - Porphyrinoids

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Möbius antiaromatic bisphosphorus complexes of [30]hexaphyrins

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