Magnetism in a helicate complexes arising with the tetradentate ligand

Hitomi Ohmagari; Manabu Nakaya; Kaisei Tanaka; Hikaru Zenno; Ryohei Akiyoshi; Yoshihiro Sekine; Yingjie Zhang; Kil Sik Min; Miki Hasegawa; Leonard F. Lindoy; Shinya Hayami

doi:10.1039/d0dt03990j

Magnetism in a helicate complexes arising with the tetradentate ligand

Hitomi Ohmagari, Manabu Nakaya, Kaisei Tanaka, Hikaru Zenno, Ryohei Akiyoshi, Yoshihiro Sekine, Yingjie Zhang, Kil Sik Min, Miki Hasegawa, Leonard F. Lindoy, Shinya Hayami

Department of Chemical Science Education

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

Original language	English
Pages (from-to)	494-498
Number of pages	5
Journal	Dalton Transactions
Volume	50
Issue number	2
DOIs	https://doi.org/10.1039/d0dt03990j
State	Published - 14 Jan 2021

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title = "Magnetism in a helicate complexes arising with the tetradentate ligand",

abstract = "The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.",

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doi = "10.1039/d0dt03990j",

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T1 - Magnetism in a helicate complexes arising with the tetradentate ligand

AU - Ohmagari, Hitomi

AU - Nakaya, Manabu

AU - Tanaka, Kaisei

AU - Zenno, Hikaru

AU - Akiyoshi, Ryohei

AU - Sekine, Yoshihiro

AU - Zhang, Yingjie

AU - Min, Kil Sik

AU - Hasegawa, Miki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

PY - 2021/1/14

Y1 - 2021/1/14

N2 - The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

AB - The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

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U2 - 10.1039/d0dt03990j

DO - 10.1039/d0dt03990j

M3 - Article

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SN - 1477-9226

VL - 50

SP - 494

EP - 498

JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Magnetism in a helicate complexes arising with the tetradentate ligand

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