Magnetism in a helicate complexes arising with the tetradentate ligand

Hitomi Ohmagari; Manabu Nakaya; Kaisei Tanaka; Hikaru Zenno; Ryohei Akiyoshi; Yoshihiro Sekine; Yingjie Zhang; Kil Sik Min; Miki Hasegawa; Leonard F. Lindoy; Shinya Hayami

doi:10.1039/d0dt03990j

Magnetism in a helicate complexes arising with the tetradentate ligand

Hitomi Ohmagari
, Manabu Nakaya
, Kaisei Tanaka
, Hikaru Zenno
, Ryohei Akiyoshi
, Yoshihiro Sekine
, Yingjie Zhang
, Kil Sik Min
, Miki Hasegawa
, Leonard F. Lindoy
, Shinya Hayami

Department of Chemical Science Education

Aoyama Gakuin University
Josai University
Kumamoto University
Australian Nuclear Science and Technology Organisation
The University of Sydney

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

Original language	English
Pages (from-to)	494-498
Number of pages	5
Journal	Dalton Transactions
Volume	50
Issue number	2
DOIs	https://doi.org/10.1039/d0dt03990j
State	Published - 14 Jan 2021

Access to Document

10.1039/d0dt03990j

Cite this

@article{58e77729622f49d993ff894f62311780,

title = "Magnetism in a helicate complexes arising with the tetradentate ligand",

abstract = "The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.",

author = "Hitomi Ohmagari and Manabu Nakaya and Kaisei Tanaka and Hikaru Zenno and Ryohei Akiyoshi and Yoshihiro Sekine and Yingjie Zhang and Min, \{Kil Sik\} and Miki Hasegawa and Lindoy, \{Leonard F.\} and Shinya Hayami",

note = "Publisher Copyright: {\textcopyright} 2021 The Royal Society of Chemistry.",

year = "2021",

month = jan,

day = "14",

doi = "10.1039/d0dt03990j",

language = "English",

volume = "50",

pages = "494--498",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - Magnetism in a helicate complexes arising with the tetradentate ligand

AU - Ohmagari, Hitomi

AU - Nakaya, Manabu

AU - Tanaka, Kaisei

AU - Zenno, Hikaru

AU - Akiyoshi, Ryohei

AU - Sekine, Yoshihiro

AU - Zhang, Yingjie

AU - Min, Kil Sik

AU - Hasegawa, Miki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

PY - 2021/1/14

Y1 - 2021/1/14

N2 - The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

AB - The synthesis of [M(dimphen)(NCS)2] (1; M = FeII), (2; M = CoII), (3; M = MnII) and [Fe(dimphen)(NCSe)2] (4), where dimphen = [1,2-bis(9-methyl-1,10-phenanthrolin-2-yl)ethane], are reported. The crystal packing structures of 1-3, show intermolecular π-π stacking and NCS⋯SCN interactions. The complex 1 shows ferromagnetic interaction, and the complex 2 displays single-molecular magnet behaviour.

UR - https://www.scopus.com/pages/publications/85099728867

U2 - 10.1039/d0dt03990j

DO - 10.1039/d0dt03990j

M3 - Article

C2 - 33367344

AN - SCOPUS:85099728867

SN - 1477-9226

VL - 50

SP - 494

EP - 498

JO - Dalton Transactions

JF - Dalton Transactions

IS - 2

ER -

Magnetism in a helicate complexes arising with the tetradentate ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this