[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee; Jeffrey B. Bonanno; Tony Hascall; Joseph Cordaro; Juliet M. Hahn; Gerard Parkin

doi:10.1039/a900173e

[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Hyosun Lee
, Jeffrey B. Bonanno
, Tony Hascall
, Joseph Cordaro
, Juliet M. Hahn
, Gerard Parkin

Columbia University

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A series of permethylated [Me₂Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me₂Si(C₅Me₄)]TiR₂ are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me₂Si(C₅Me₄)(C₅Me ₃CH₂)]TiR.

Original language	English
Pages (from-to)	1365-1368
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/a900173e
State	Published - 7 May 1999

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@article{fbf1036de3a742c3adbdceb173d7329b,

title = "[Me2Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character",

abstract = "A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.",

author = "Hyosun Lee and Bonanno, \{Jeffrey B.\} and Tony Hascall and Joseph Cordaro and Hahn, \{Juliet M.\} and Gerard Parkin",

year = "1999",

month = may,

day = "7",

doi = "10.1039/a900173e",

language = "English",

pages = "1365--1368",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "9",

}

[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character. / Lee, Hyosun; Bonanno, Jeffrey B.; Hascall, Tony et al.
In: Journal of the Chemical Society. Dalton Transactions, No. 9, 07.05.1999, p. 1365-1368.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [Me2Si] ansa bridged complexes of permethyltitanocene

T2 - Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

AU - Lee, Hyosun

AU - Bonanno, Jeffrey B.

AU - Hascall, Tony

AU - Cordaro, Joseph

AU - Hahn, Juliet M.

AU - Parkin, Gerard

PY - 1999/5/7

Y1 - 1999/5/7

N2 - A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

AB - A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray diffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me 3CH2)]TiR.

UR - https://www.scopus.com/pages/publications/33749100561

U2 - 10.1039/a900173e

DO - 10.1039/a900173e

M3 - Article

AN - SCOPUS:33749100561

SN - 1470-479X

SP - 1365

EP - 1368

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 9

ER -

[Me₂Si] ansa bridged complexes of permethyltitanocene: Synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

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