Metal-ion metathesis in metal-organic frameworks: A synthetic route to new metal-organic frameworks

Yonghwi Kim, Sunirban Das, Saurav Bhattacharya, Soonsang Hong, Min Gyu Kim, Minyoung Yoon, Srinivasan Natarajan, Kimoon Kim

Research output: Contribution to journalArticlepeer-review

85 Scopus citations

Abstract

A porous metal-organic framework, Mn(H3O)[(Mn 4Cl)3(hmtt)8] (POST-65), was prepared by the reaction of 5,5′,10,10′,15,15′-hexamethyltruxene-2,7,12- tricarboxylic acid (H3hmtt) with MnCl2 under solvothermal conditions. POST-65(Mn) was subjected to post-synthetic modification with Fe, Co, Ni, and Cu according to an ion-exchange method that r

Original languageEnglish
Pages (from-to)16642-16648
Number of pages7
JournalChemistry - A European Journal
Volume18
Issue number52
DOIs
StatePublished - 21 Dec 2012

Keywords

  • adsorption
  • magnetism
  • metal-ion exchange
  • metal-organic frameworks
  • metathesis

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