Metal-ion metathesis in metal-organic frameworks: A synthetic route to new metal-organic frameworks

Yonghwi Kim; Sunirban Das; Saurav Bhattacharya; Soonsang Hong; Min Gyu Kim; Minyoung Yoon; Srinivasan Natarajan; Kimoon Kim

doi:10.1002/chem.201202899

Metal-ion metathesis in metal-organic frameworks: A synthetic route to new metal-organic frameworks

Yonghwi Kim
, Sunirban Das
, Saurav Bhattacharya
, Soonsang Hong
, Min Gyu Kim
, Minyoung Yoon
, Srinivasan Natarajan
, Kimoon Kim

Pohang University of Science and Technology
Indian Institute of Science Bangalore

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

A porous metal-organic framework, Mn(H₃O)[(Mn ₄Cl)₃(hmtt)₈] (POST-65), was prepared by the reaction of 5,5′,10,10′,15,15′-hexamethyltruxene-2,7,12- tricarboxylic acid (H₃hmtt) with MnCl₂ under solvothermal conditions. POST-65(Mn) was subjected to post-synthetic modification with Fe, Co, Ni, and Cu according to an ion-exchange method that r

Original language	English
Pages (from-to)	16642-16648
Number of pages	7
Journal	Chemistry - A European Journal
Volume	18
Issue number	52
DOIs	https://doi.org/10.1002/chem.201202899
State	Published - 21 Dec 2012

Keywords

adsorption
magnetism
metal-ion exchange
metal-organic frameworks
metathesis

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10.1002/chem.201202899

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title = "Metal-ion metathesis in metal-organic frameworks: A synthetic route to new metal-organic frameworks",

abstract = "A porous metal-organic framework, Mn(H3O)[(Mn 4Cl)3(hmtt)8] (POST-65), was prepared by the reaction of 5,5′,10,10′,15,15′-hexamethyltruxene-2,7,12- tricarboxylic acid (H3hmtt) with MnCl2 under solvothermal conditions. POST-65(Mn) was subjected to post-synthetic modification with Fe, Co, Ni, and Cu according to an ion-exchange method that r",

keywords = "adsorption, magnetism, metal-ion exchange, metal-organic frameworks, metathesis",

author = "Yonghwi Kim and Sunirban Das and Saurav Bhattacharya and Soonsang Hong and Kim, \{Min Gyu\} and Minyoung Yoon and Srinivasan Natarajan and Kimoon Kim",

year = "2012",

month = dec,

day = "21",

doi = "10.1002/chem.201202899",

language = "English",

volume = "18",

pages = "16642--16648",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

number = "52",

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TY - JOUR

T1 - Metal-ion metathesis in metal-organic frameworks

T2 - A synthetic route to new metal-organic frameworks

AU - Kim, Yonghwi

AU - Das, Sunirban

AU - Bhattacharya, Saurav

AU - Hong, Soonsang

AU - Kim, Min Gyu

AU - Yoon, Minyoung

AU - Natarajan, Srinivasan

AU - Kim, Kimoon

PY - 2012/12/21

Y1 - 2012/12/21

N2 - A porous metal-organic framework, Mn(H3O)[(Mn 4Cl)3(hmtt)8] (POST-65), was prepared by the reaction of 5,5′,10,10′,15,15′-hexamethyltruxene-2,7,12- tricarboxylic acid (H3hmtt) with MnCl2 under solvothermal conditions. POST-65(Mn) was subjected to post-synthetic modification with Fe, Co, Ni, and Cu according to an ion-exchange method that r

AB - A porous metal-organic framework, Mn(H3O)[(Mn 4Cl)3(hmtt)8] (POST-65), was prepared by the reaction of 5,5′,10,10′,15,15′-hexamethyltruxene-2,7,12- tricarboxylic acid (H3hmtt) with MnCl2 under solvothermal conditions. POST-65(Mn) was subjected to post-synthetic modification with Fe, Co, Ni, and Cu according to an ion-exchange method that r

KW - adsorption

KW - magnetism

KW - metal-ion exchange

KW - metal-organic frameworks

KW - metathesis

UR - https://www.scopus.com/pages/publications/84872911741

U2 - 10.1002/chem.201202899

DO - 10.1002/chem.201202899

M3 - Article

AN - SCOPUS:84872911741

SN - 0947-6539

VL - 18

SP - 16642

EP - 16648

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 52

ER -

Metal-ion metathesis in metal-organic frameworks: A synthetic route to new metal-organic frameworks

Abstract

Keywords

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