Mineral transformation and dissolution of jarosite coprecipitated with hazardous oxyanions and their mobility changes

Jarosite coprecipitation with hazardous oxyanions can attenuate the concentrations of these elements in acid mine drainage. However, jarosite can be easily transformed to goethite with changes in geochemical conditions. Consequently, the released oxyanions can greatly affect environments. The changes in the mineralogy and mobility of five oxyanions, namely AsO₄, SeO₃, SeO₄, MoO₄, and CrO₄, which were coprecipitated with jarosite, are investigated herein during the mineral transformation. Our results show that the oxyanion species and the pH values greatly affect the mineral transformation and dissolution rates of jarosite-containing oxyanions. The transformation and dissolution rates of the jarosite samples at pH 8 are noticeably higher than those at pH 4. The X-ray diffraction results show that the CrO₄ and SeO₄ jarosites are as effectively transformed to goethite as the jarosite without oxyanions, while the SeO₃ and AsO₄ jarosites are least transformed, resulting in different sulfate and oxyanion concentrations in the solution. The oxyanions in jarosite are the main controlling factor in the mineral transformation and dissolution rates. In acid mine drainage, although CrO₄ is easily attenuated by the jarosite precipitation, it has the highest mobility during the goethite transformation. On the contrary, AsO₄ shows the opposite case.