Modulation of dual electronic circuits of [26]hexaphyrins using internal aromatic straps

Hirotaka Mori; Jong Min Lim; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.201308545

Modulation of dual electronic circuits of [26]hexaphyrins using internal aromatic straps

Hirotaka Mori, Jong Min Lim, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.

Original language	English
Pages (from-to)	12997-13001
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	49
DOIs	https://doi.org/10.1002/anie.201308545
State	Published - 2 Dec 2013

Keywords

annulenoannulenes
conjugation
hexaphyrins
internal bridges
porphyrinoids

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title = "Modulation of dual electronic circuits of [26]hexaphyrins using internal aromatic straps",

abstract = "Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.",

keywords = "annulenoannulenes, conjugation, hexaphyrins, internal bridges, porphyrinoids",

author = "Hirotaka Mori and Lim, {Jong Min} and Dongho Kim and Atsuhiro Osuka",

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AU - Mori, Hirotaka

AU - Lim, Jong Min

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2013/12/2

Y1 - 2013/12/2

N2 - Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.

AB - Internal bridges: [26]Hexaphyrins with an aromatic strap in 5,20 position have two potentially cyclic conjugated networks, that is, [18]porphyrin and [26]hexaphyrin (see picture), and show a formal analogy with [18]annuleno[18]annulens. 1,3-Phenylene-, 2,5-thienylene-, and 2,5-pyrrylene-bridged [26]hexaphyrins have been synthesized and characterized.

KW - annulenoannulenes

KW - conjugation

KW - hexaphyrins

KW - internal bridges

KW - porphyrinoids

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 49

ER -

Modulation of dual electronic circuits of [26]hexaphyrins using internal aromatic straps

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Keywords

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