Morphology and conducting property of Ag/poly(pyrrole) composite nanoparticles: Effect of polymeric stabilizers

Yeon Jae Jung; Patakamuri Govindaiah; Sung Wook Choi; In Woo Cheong; Jung Hyun Kim

doi:10.1016/j.synthmet.2011.07.009

Morphology and conducting property of Ag/poly(pyrrole) composite nanoparticles: Effect of polymeric stabilizers

Yeon Jae Jung, Patakamuri Govindaiah, Sung Wook Choi, In Woo Cheong, Jung Hyun Kim

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Ag/poly(pyrrole) (Ag/PPy) composite nanoparticles were successfully prepared using poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) or poly(N-vinylpyrrolidone) (PVP) as a polymeric stabilizer via one-pot oxidative polymerization in an aqueous medium. During the polymerization, pyrrole monomer is polymerized into PPy at the aggregates of the polymeric stabilizers by Ag⁺ ions, and which are reduced to Ag⁰ metal state by pyrrole with coordination bonding between the polymeric stabilizers and Ag⁺ ions. UV-vis spectrophotometry confirmed that the coordination complex affected the reduction rate of Ag⁺ ions and the reduction rate of Ag⁺ ions in PSSMA system was slower than that of PVP due to the electron withdrawing nature of PSSMA. Effect of the structural difference between PVP and PSSMA on the morphology and electrical conductivity of Ag/PPy composite nanoparticles was studied and compared.

Original language	English
Pages (from-to)	1991-1995
Number of pages	5
Journal	Synthetic Metals
Volume	161
Issue number	17-18
DOIs	https://doi.org/10.1016/j.synthmet.2011.07.009
State	Published - Sep 2011

Keywords

Ag/poly(pyrrole)
Electrical conductivity
Morphology
Nanoparticles
Oxidative polymerization
Polymeric stabilizer

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10.1016/j.synthmet.2011.07.009

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title = "Morphology and conducting property of Ag/poly(pyrrole) composite nanoparticles: Effect of polymeric stabilizers",

abstract = "Ag/poly(pyrrole) (Ag/PPy) composite nanoparticles were successfully prepared using poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) or poly(N-vinylpyrrolidone) (PVP) as a polymeric stabilizer via one-pot oxidative polymerization in an aqueous medium. During the polymerization, pyrrole monomer is polymerized into PPy at the aggregates of the polymeric stabilizers by Ag+ ions, and which are reduced to Ag0 metal state by pyrrole with coordination bonding between the polymeric stabilizers and Ag+ ions. UV-vis spectrophotometry confirmed that the coordination complex affected the reduction rate of Ag+ ions and the reduction rate of Ag+ ions in PSSMA system was slower than that of PVP due to the electron withdrawing nature of PSSMA. Effect of the structural difference between PVP and PSSMA on the morphology and electrical conductivity of Ag/PPy composite nanoparticles was studied and compared.",

keywords = "Ag/poly(pyrrole), Electrical conductivity, Morphology, Nanoparticles, Oxidative polymerization, Polymeric stabilizer",

author = "Jung, {Yeon Jae} and Patakamuri Govindaiah and Choi, {Sung Wook} and Cheong, {In Woo} and Kim, {Jung Hyun}",

year = "2011",

month = sep,

doi = "10.1016/j.synthmet.2011.07.009",

language = "English",

volume = "161",

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journal = "Synthetic Metals",

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TY - JOUR

T1 - Morphology and conducting property of Ag/poly(pyrrole) composite nanoparticles

T2 - Effect of polymeric stabilizers

AU - Jung, Yeon Jae

AU - Govindaiah, Patakamuri

AU - Choi, Sung Wook

AU - Cheong, In Woo

AU - Kim, Jung Hyun

PY - 2011/9

Y1 - 2011/9

N2 - Ag/poly(pyrrole) (Ag/PPy) composite nanoparticles were successfully prepared using poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) or poly(N-vinylpyrrolidone) (PVP) as a polymeric stabilizer via one-pot oxidative polymerization in an aqueous medium. During the polymerization, pyrrole monomer is polymerized into PPy at the aggregates of the polymeric stabilizers by Ag+ ions, and which are reduced to Ag0 metal state by pyrrole with coordination bonding between the polymeric stabilizers and Ag+ ions. UV-vis spectrophotometry confirmed that the coordination complex affected the reduction rate of Ag+ ions and the reduction rate of Ag+ ions in PSSMA system was slower than that of PVP due to the electron withdrawing nature of PSSMA. Effect of the structural difference between PVP and PSSMA on the morphology and electrical conductivity of Ag/PPy composite nanoparticles was studied and compared.

AB - Ag/poly(pyrrole) (Ag/PPy) composite nanoparticles were successfully prepared using poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA) or poly(N-vinylpyrrolidone) (PVP) as a polymeric stabilizer via one-pot oxidative polymerization in an aqueous medium. During the polymerization, pyrrole monomer is polymerized into PPy at the aggregates of the polymeric stabilizers by Ag+ ions, and which are reduced to Ag0 metal state by pyrrole with coordination bonding between the polymeric stabilizers and Ag+ ions. UV-vis spectrophotometry confirmed that the coordination complex affected the reduction rate of Ag+ ions and the reduction rate of Ag+ ions in PSSMA system was slower than that of PVP due to the electron withdrawing nature of PSSMA. Effect of the structural difference between PVP and PSSMA on the morphology and electrical conductivity of Ag/PPy composite nanoparticles was studied and compared.

KW - Ag/poly(pyrrole)

KW - Electrical conductivity

KW - Morphology

KW - Nanoparticles

KW - Oxidative polymerization

KW - Polymeric stabilizer

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U2 - 10.1016/j.synthmet.2011.07.009

DO - 10.1016/j.synthmet.2011.07.009

M3 - Article

AN - SCOPUS:80052261586

SN - 0379-6779

VL - 161

SP - 1991

EP - 1995

JO - Synthetic Metals

JF - Synthetic Metals

IS - 17-18

ER -

Morphology and conducting property of Ag/poly(pyrrole) composite nanoparticles: Effect of polymeric stabilizers

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Keywords

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