New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Min Jae Sung; Yebyeol Kim; Sang Bong Lee; Gi Back Lee; Tae Kyu An; Hyojung Cha; Se Hyun Kim; Chan Eon Park; Yun Hi Kim

doi:10.1016/j.dyepig.2015.09.026

New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Min Jae Sung, Yebyeol Kim, Sang Bong Lee, Gi Back Lee, Tae Kyu An, Hyojung Cha, Se Hyun Kim, Chan Eon Park, Yun Hi Kim

Major in Hydrogen & Renewable Energy

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (T_ann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of T_ann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10^-3 cm²/(V·s)).

Original language	English
Pages (from-to)	316-322
Number of pages	7
Journal	Dyes and Pigments
Volume	125
DOIs	https://doi.org/10.1016/j.dyepig.2015.09.026
State	Published - Feb 2016

Keywords

Dithienophosphole
Donor-acceptor (D-A) architecture
Organic field effect transistor (OFET)
Polymeric semiconductor
Well ordered crystalline structure
X-ray diffraction

Access to Document

10.1016/j.dyepig.2015.09.026

Cite this

@article{abcfaaa7a8f84f37b4e97a2f0a122430,

title = "New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET",

abstract = "Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).",

keywords = "Dithienophosphole, Donor-acceptor (D-A) architecture, Organic field effect transistor (OFET), Polymeric semiconductor, Well ordered crystalline structure, X-ray diffraction",

author = "Sung, {Min Jae} and Yebyeol Kim and Lee, {Sang Bong} and Lee, {Gi Back} and An, {Tae Kyu} and Hyojung Cha and Kim, {Se Hyun} and Park, {Chan Eon} and Kim, {Yun Hi}",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd.",

year = "2016",

month = feb,

doi = "10.1016/j.dyepig.2015.09.026",

language = "English",

volume = "125",

pages = "316--322",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - New dithienophosphole-based donor-acceptor alternating copolymers

T2 - Synthesis and structure property relationships in OFET

AU - Sung, Min Jae

AU - Kim, Yebyeol

AU - Lee, Sang Bong

AU - Lee, Gi Back

AU - An, Tae Kyu

AU - Cha, Hyojung

AU - Kim, Se Hyun

AU - Park, Chan Eon

AU - Kim, Yun Hi

PY - 2016/2

Y1 - 2016/2

N2 - Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).

AB - Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).

KW - Dithienophosphole

KW - Donor-acceptor (D-A) architecture

KW - Organic field effect transistor (OFET)

KW - Polymeric semiconductor

KW - Well ordered crystalline structure

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=84947093424&partnerID=8YFLogxK

U2 - 10.1016/j.dyepig.2015.09.026

DO - 10.1016/j.dyepig.2015.09.026

M3 - Article

AN - SCOPUS:84947093424

SN - 0143-7208

VL - 125

SP - 316

EP - 322

JO - Dyes and Pigments

JF - Dyes and Pigments

ER -

New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this