New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Min Jae Sung; Yebyeol Kim; Sang Bong Lee; Gi Back Lee; Tae Kyu An; Hyojung Cha; Se Hyun Kim; Chan Eon Park; Yun Hi Kim

doi:10.1016/j.dyepig.2015.09.026

New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Min Jae Sung
, Yebyeol Kim
, Sang Bong Lee
, Gi Back Lee
, Tae Kyu An
, Hyojung Cha
, Se Hyun Kim
, Chan Eon Park
, Yun Hi Kim

Major in Hydrogen & Renewable Energy

Gyeongsang National University
Pohang University of Science and Technology
Korea National University of Transportation
Yeungnam University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (T_ann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of T_ann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10^-3 cm²/(V·s)).

Original language	English
Pages (from-to)	316-322
Number of pages	7
Journal	Dyes and Pigments
Volume	125
DOIs	https://doi.org/10.1016/j.dyepig.2015.09.026
State	Published - Feb 2016

Keywords

Dithienophosphole
Donor-acceptor (D-A) architecture
Organic field effect transistor (OFET)
Polymeric semiconductor
Well ordered crystalline structure
X-ray diffraction

Access to Document

10.1016/j.dyepig.2015.09.026

Cite this

@article{abcfaaa7a8f84f37b4e97a2f0a122430,

title = "New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET",

abstract = "Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).",

keywords = "Dithienophosphole, Donor-acceptor (D-A) architecture, Organic field effect transistor (OFET), Polymeric semiconductor, Well ordered crystalline structure, X-ray diffraction",

author = "Sung, \{Min Jae\} and Yebyeol Kim and Lee, \{Sang Bong\} and Lee, \{Gi Back\} and An, \{Tae Kyu\} and Hyojung Cha and Kim, \{Se Hyun\} and Park, \{Chan Eon\} and Kim, \{Yun Hi\}",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd.",

year = "2016",

month = feb,

doi = "10.1016/j.dyepig.2015.09.026",

language = "English",

volume = "125",

pages = "316--322",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - New dithienophosphole-based donor-acceptor alternating copolymers

T2 - Synthesis and structure property relationships in OFET

AU - Sung, Min Jae

AU - Kim, Yebyeol

AU - Lee, Sang Bong

AU - Lee, Gi Back

AU - An, Tae Kyu

AU - Cha, Hyojung

AU - Kim, Se Hyun

AU - Park, Chan Eon

AU - Kim, Yun Hi

PY - 2016/2

Y1 - 2016/2

N2 - Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).

AB - Two donor-acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor-acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (Tann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200°C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 × 10-3 cm2/(V·s)).

KW - Dithienophosphole

KW - Donor-acceptor (D-A) architecture

KW - Organic field effect transistor (OFET)

KW - Polymeric semiconductor

KW - Well ordered crystalline structure

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84947093424

U2 - 10.1016/j.dyepig.2015.09.026

DO - 10.1016/j.dyepig.2015.09.026

M3 - Article

AN - SCOPUS:84947093424

SN - 0143-7208

VL - 125

SP - 316

EP - 322

JO - Dyes and Pigments

JF - Dyes and Pigments

ER -

New dithienophosphole-based donor-acceptor alternating copolymers: Synthesis and structure property relationships in OFET

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this