Abstract
The addition of Si even in trace quantity (0.04 wt%) refined the spangle structure in the outermost part of a Zn-2Al-3Mg coating by precipitating Mg2Si and Zn-Al intermetallic phases on the ternary eutectic areas. In contrast to the conventional interface control of the Zn-Al-Mg-Si coating, this surface-controlled technique is a break-through in that it suppresses localized corrosion in the ternary eutectic areas of the outer surface by making minimal use of Si. Moreover, the surface coverage by corrosion products with a bi-layer structure and inhibiting property, following the rapid sacrificial dissolution of intermetallic phases, provided long-term corrosion resistance of steel.
Original language | English |
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Article number | 153868 |
Journal | Applied Surface Science |
Volume | 598 |
DOIs | |
State | Published - 1 Oct 2022 |
Keywords
- Corrosion
- Hot-dip galvanized steel
- MgSi
- Scanning electron microscopy
- Silicon
- Zn-Al-Mg alloy coatings