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Nickel phosphate molecular sieves VSB-5 as heterogeneous catalysts for synthesis of monosaccharides from formaldehyde and dihydroxyacetone

  • Irina V. Delidovich
  • , Maria N. Timofeeva
  • , Alexander Yu Orlov
  • , Valentina N. Panchenko
  • , Zubair Hasan
  • , Sung Hwa Jhung
  • , Oxana P. Taran
  • , Valentin N. Parmon
  • RAS - Boreskov Institute of Catalysis, Siberian Branch
  • Novosibirsk State Technichal University
  • Novosibirsk State University
  • Kyungpook National University

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe-VSB-5) in neutral aqueous medium. In the presence of VSB-5 the main products are erythrulose and 3-pentulose, while Fe-VSB-5 favours the formation of only erythrulose.

Original languageEnglish
Pages (from-to)2201-2204
Number of pages4
JournalNew Journal of Chemistry
Volume36
Issue number11
DOIs
StatePublished - Nov 2012

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