TY - JOUR
T1 - Novel Tb3+ doped borophosphate glass scintillator for X-ray imaging
AU - Khrongchaiyaphum, F.
AU - Wantana, N.
AU - Kaewnuam, E.
AU - Pakawanit, P.
AU - Phoovasawat, C.
AU - Vittayakorn, N.
AU - Chanthima, N.
AU - Phongsa, A.
AU - Intachai, N.
AU - Kothan, S.
AU - Kim, H. J.
AU - Kaewkhao, J.
N1 - Publisher Copyright:
© 2024 Elsevier Ltd
PY - 2024/10
Y1 - 2024/10
N2 - In this study, we introduce an efficient green-emitting material made from Tb3+ doped borophosphate scintillating glass for X-ray imaging. An influence of Tb2O3 concentration on the physical, optical, luminescent, and scintillation properties of glasses were investigated. The glass density and refractive index increase, while the molar volume and Tb3+ inter-ionic distance decreases with Tb2O3 addition. These glasses absorb the photons in range of UV, Vis, and NIR. The excitations by UV and X-ray on glasses causes the strong green emission centered around 545 nm by the 5D4 → 7F5 transition of Tb3+. The energy transfer from Gd3+ to Tb3+ was occurred in this emission. The glass doped with 4 mol% of Tb2O3 demonstrates the highest emission intensity at 545 nm due to the concentration quenching. The decay time of glasses are in few milliseconds. The integral X-ray scintillation efficiency of 4 mol% doped glass is 52% compared to that of BGO crystal. Additionally, this glass was proceeded in the X-ray imaging and yielded the image with satisfied resolution, characteristics and MTF values, compared to that obtained from YAG:Ce crystal. The developed glass has a potential for X-ray imaging applications, especially in the medical imaging, flaw detection, and security inspection.
AB - In this study, we introduce an efficient green-emitting material made from Tb3+ doped borophosphate scintillating glass for X-ray imaging. An influence of Tb2O3 concentration on the physical, optical, luminescent, and scintillation properties of glasses were investigated. The glass density and refractive index increase, while the molar volume and Tb3+ inter-ionic distance decreases with Tb2O3 addition. These glasses absorb the photons in range of UV, Vis, and NIR. The excitations by UV and X-ray on glasses causes the strong green emission centered around 545 nm by the 5D4 → 7F5 transition of Tb3+. The energy transfer from Gd3+ to Tb3+ was occurred in this emission. The glass doped with 4 mol% of Tb2O3 demonstrates the highest emission intensity at 545 nm due to the concentration quenching. The decay time of glasses are in few milliseconds. The integral X-ray scintillation efficiency of 4 mol% doped glass is 52% compared to that of BGO crystal. Additionally, this glass was proceeded in the X-ray imaging and yielded the image with satisfied resolution, characteristics and MTF values, compared to that obtained from YAG:Ce crystal. The developed glass has a potential for X-ray imaging applications, especially in the medical imaging, flaw detection, and security inspection.
KW - Borophosphate glass
KW - Luminescence
KW - Terbium
KW - X-ray imaging
UR - http://www.scopus.com/inward/record.url?scp=85196669057&partnerID=8YFLogxK
U2 - 10.1016/j.radphyschem.2024.111851
DO - 10.1016/j.radphyschem.2024.111851
M3 - Article
AN - SCOPUS:85196669057
SN - 0969-806X
VL - 223
JO - Radiation Physics and Chemistry
JF - Radiation Physics and Chemistry
M1 - 111851
ER -