On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

Mark A. Hughes; Russell M. Gwilliam; Kevin Homewood; Behrad Gholipour; Daniel W. Hewak; Tae Hoon Lee; Stephen R. Elliott; Takenobu Suzuki; Yasutake Ohishi; Tomas Kohoutek; Richard J. Curry

doi:10.1364/OE.21.008101

On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

Mark A. Hughes, Russell M. Gwilliam, Kevin Homewood, Behrad Gholipour, Daniel W. Hewak, Tae Hoon Lee, Stephen R. Elliott, Takenobu Suzuki, Yasutake Ohishi, Tomas Kohoutek, Richard J. Curry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

Original language	English
Pages (from-to)	8101-8115
Number of pages	15
Journal	Optics Express
Volume	21
Issue number	7
DOIs	https://doi.org/10.1364/OE.21.008101
State	Published - 8 Apr 2013

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title = "On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses",

abstract = "Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.",

author = "Hughes, {Mark A.} and Gwilliam, {Russell M.} and Kevin Homewood and Behrad Gholipour and Hewak, {Daniel W.} and Lee, {Tae Hoon} and Elliott, {Stephen R.} and Takenobu Suzuki and Yasutake Ohishi and Tomas Kohoutek and Curry, {Richard J.}",

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T1 - On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

AU - Hughes, Mark A.

AU - Gwilliam, Russell M.

AU - Homewood, Kevin

AU - Gholipour, Behrad

AU - Hewak, Daniel W.

AU - Lee, Tae Hoon

AU - Elliott, Stephen R.

AU - Suzuki, Takenobu

AU - Ohishi, Yasutake

AU - Kohoutek, Tomas

AU - Curry, Richard J.

PY - 2013/4/8

Y1 - 2013/4/8

N2 - Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

AB - Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

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On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

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