On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

Mark A. Hughes; Russell M. Gwilliam; Kevin Homewood; Behrad Gholipour; Daniel W. Hewak; Tae Hoon Lee; Stephen R. Elliott; Takenobu Suzuki; Yasutake Ohishi; Tomas Kohoutek; Richard J. Curry

doi:10.1364/OE.21.008101

On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

Mark A. Hughes
, Russell M. Gwilliam
, Kevin Homewood
, Behrad Gholipour
, Daniel W. Hewak
, Tae Hoon Lee
, Stephen R. Elliott
, Takenobu Suzuki
, Yasutake Ohishi
, Tomas Kohoutek
, Richard J. Curry

University of Surrey
University of Southampton
University of Cambridge
Toyota Technological Institute
University of Pardubice

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

Original language	English
Pages (from-to)	8101-8115
Number of pages	15
Journal	Optics Express
Volume	21
Issue number	7
DOIs	https://doi.org/10.1364/OE.21.008101
State	Published - 8 Apr 2013

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title = "On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses",

abstract = "Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.",

author = "Hughes, \{Mark A.\} and Gwilliam, \{Russell M.\} and Kevin Homewood and Behrad Gholipour and Hewak, \{Daniel W.\} and Lee, \{Tae Hoon\} and Elliott, \{Stephen R.\} and Takenobu Suzuki and Yasutake Ohishi and Tomas Kohoutek and Curry, \{Richard J.\}",

year = "2013",

month = apr,

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doi = "10.1364/OE.21.008101",

language = "English",

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T1 - On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

AU - Hughes, Mark A.

AU - Gwilliam, Russell M.

AU - Homewood, Kevin

AU - Gholipour, Behrad

AU - Hewak, Daniel W.

AU - Lee, Tae Hoon

AU - Elliott, Stephen R.

AU - Suzuki, Takenobu

AU - Ohishi, Yasutake

AU - Kohoutek, Tomas

AU - Curry, Richard J.

PY - 2013/4/8

Y1 - 2013/4/8

N2 - Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

AB - Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi2+ and Bin clusters, respectively. Very similar centers are present in Bi-and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasses display new PL bands, indicating that new Bi centers are formed. Bi-related PL bands have been observed in glasses with very similar compositions to those in which carrier-type reversal has been observed, indicating that these phenomena are related to the same Bi centers, which we suggest are interstitial Bi2+ and Bi clusters.

UR - https://www.scopus.com/pages/publications/84875989685

U2 - 10.1364/OE.21.008101

DO - 10.1364/OE.21.008101

M3 - Article

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AN - SCOPUS:84875989685

SN - 1094-4087

VL - 21

SP - 8101

EP - 8115

JO - Optics Express

JF - Optics Express

IS - 7

ER -

On the analogy between photoluminescence and carrier-type reversal in Bi-and Pb-doped glasses

Abstract

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