Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

Purna Chandra Rao; Prabu Mani; Younghu Son; Jiyun Kim; Minyoung Yoon

doi:10.1039/d1cc03721h

Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

Purna Chandra Rao
, Prabu Mani
, Younghu Son
, Jiyun Kim
, Minyoung Yoon

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

Original language	English
Pages (from-to)	10158-10161
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	79
DOIs	https://doi.org/10.1039/d1cc03721h
State	Published - 11 Oct 2021

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10.1039/d1cc03721h

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abstract = "We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.",

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T1 - Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

AU - Rao, Purna Chandra

AU - Mani, Prabu

AU - Son, Younghu

AU - Kim, Jiyun

AU - Yoon, Minyoung

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/10/11

Y1 - 2021/10/11

N2 - We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

AB - We report epitaxially grown new two-dimensional metal-organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.

UR - https://www.scopus.com/pages/publications/85115721467

U2 - 10.1039/d1cc03721h

DO - 10.1039/d1cc03721h

M3 - Article

C2 - 34505597

AN - SCOPUS:85115721467

SN - 1359-7345

VL - 57

SP - 10158

EP - 10161

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Organic guest molecule induced ultrafast breathing of an epitaxially grown metal-organic framework on a self-assembled monolayer

Abstract

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