Palladium-catalyzed carbonylative cyclization of β-bromo-α, β-unsaturated carboxylic acids with primary amines leading to N-alkylmaleimides

Hye Kyung Lee; Chan Sik Cho

doi:10.1002/aoc.2836

Palladium-catalyzed carbonylative cyclization of β-bromo-α, β-unsaturated carboxylic acids with primary amines leading to N-alkylmaleimides

Hye Kyung Lee, Chan Sik Cho

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Review article › peer-review

14 Scopus citations

Abstract

Cyclic β-bromo-α,β-unsaturated carboxylic acids are carbonylatively cyclized with primary amines under carbon monoxide pressure in MeCN in the presence of a catalytic amount of PdCl ₂(PPh ₃) ₂ to give N-alkylmaleimides.

Original language	English
Pages (from-to)	185-188
Number of pages	4
Journal	Applied Organometallic Chemistry
Volume	26
Issue number	4
DOIs	https://doi.org/10.1002/aoc.2836
State	Published - Apr 2012

Keywords

β-bromo-α,β-unsaturated carboxylic acids
carbonylative cyclization
N-alkylmaleimides
palladium catalyst
primary amines

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10.1002/aoc.2836

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title = "Palladium-catalyzed carbonylative cyclization of β-bromo-α, β-unsaturated carboxylic acids with primary amines leading to N-alkylmaleimides",

abstract = "Cyclic β-bromo-α,β-unsaturated carboxylic acids are carbonylatively cyclized with primary amines under carbon monoxide pressure in MeCN in the presence of a catalytic amount of PdCl 2(PPh 3) 2 to give N-alkylmaleimides.",

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AU - Cho, Chan Sik

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AB - Cyclic β-bromo-α,β-unsaturated carboxylic acids are carbonylatively cyclized with primary amines under carbon monoxide pressure in MeCN in the presence of a catalytic amount of PdCl 2(PPh 3) 2 to give N-alkylmaleimides.

KW - β-bromo-α,β-unsaturated carboxylic acids

KW - carbonylative cyclization

KW - N-alkylmaleimides

KW - palladium catalyst

KW - primary amines

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SN - 0268-2605

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JO - Applied Organometallic Chemistry

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ER -

Palladium-catalyzed carbonylative cyclization of β-bromo-α, β-unsaturated carboxylic acids with primary amines leading to N-alkylmaleimides

Abstract

Keywords

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