Pd/C-Catalyzed coupling and cyclization of β-bromo-α,β- unsaturated carboxylic acids with terminal alkynes leading to alkylidenefuranones

Chan Sik Cho, Hyo Bo Kim

Research output: Contribution to journalShort surveypeer-review

23 Scopus citations

Abstract

Palladium-catalyzed coupling of β-bromo-α,β-unsaturated carboxylic acids with terminal alkynes and subsequent regioselective 5-exo-dig cyclization produces (Z)-alkylidenefuranones in good yields.

Original languageEnglish
Pages (from-to)3264-3267
Number of pages4
JournalJournal of Organometallic Chemistry
Volume696
Issue number20
DOIs
StatePublished - 1 Oct 2011

Keywords

  • Alkylidenefuranones
  • Alkynes
  • Coupling
  • Cyclization
  • Palladium catalyst
  • β-Bromo-α,β-unsaturated carboxylic acids

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