Photoelectron spectrum of (D2O)-6 cluster anions

G. H. Lee, K. H. Bowen

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

We recorded the photoelectron spectrum of (D2O)-6 cluster anions and observed an abnormally enhanced intensity in the photoelectron transition of the low electron-binding-energy (EBE) isomer compared to the same transition in the (H2O)-6 cluster anion. This isotope effect indicates that the low EBE isomer has an excess electron not bound near to the environment of the neutral water hexamer (the so-called surface state) but bound inside the neutral water hexamer (the so-called internal state).

Original languageEnglish
Pages (from-to)76-78
Number of pages3
JournalJournal of the Korean Physical Society
Volume37
Issue number1
StatePublished - Jul 2000

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