Polymerizations of ethylene and styrene initiated with trisiloxane‐bridged dinuclear titanium metallocene/MMAO catalyst systems

Dong‐ho ‐h Lee; Keun‐byung ‐b Yoon; Eok‐hyung ‐h Lee; Seok‐kyun ‐k Noh; Gyu‐gum ‐g Byun; Chul‐soo ‐s Lee

doi:10.1002/marc.1995.030160406

Polymerizations of ethylene and styrene initiated with trisiloxane‐bridged dinuclear titanium metallocene/MMAO catalyst systems

Dong‐ho ‐h Lee, Keun‐byung ‐b Yoon, Eok‐hyung ‐h Lee, Seok‐kyun ‐k Noh, Gyu‐gum ‐g Byun, Chul‐soo ‐s Lee

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Two kinds of the trisiloxane‐bridged dinuclear titanium metallocene‐type complexes were synthesized. They are monocyclopentadienyl and biscyclopentadienyl dinuclear titanocenes with trisiloxane bridges. The above complexes with modified methylaluminoxane (MMAO) cocatalyst initiate the polymerizations of ethylene and styrene to produce high‐density polyethylene and syndiotactic polystyrene. In addition, a copolymer of ethylene and styrene was obtained.

Original language	English
Pages (from-to)	265-268
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	16
Issue number	4
DOIs	https://doi.org/10.1002/marc.1995.030160406
State	Published - Apr 1995

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title = "Polymerizations of ethylene and styrene initiated with trisiloxane‐bridged dinuclear titanium metallocene/MMAO catalyst systems",

abstract = "Two kinds of the trisiloxane‐bridged dinuclear titanium metallocene‐type complexes were synthesized. They are monocyclopentadienyl and biscyclopentadienyl dinuclear titanocenes with trisiloxane bridges. The above complexes with modified methylaluminoxane (MMAO) cocatalyst initiate the polymerizations of ethylene and styrene to produce high‐density polyethylene and syndiotactic polystyrene. In addition, a copolymer of ethylene and styrene was obtained.",

author = "Lee, {Dong‐ho ‐h} and Yoon, {Keun‐byung ‐b} and Lee, {Eok‐hyung ‐h} and Noh, {Seok‐kyun ‐k} and Byun, {Gyu‐gum ‐g} and Lee, {Chul‐soo ‐s}",

year = "1995",

month = apr,

doi = "10.1002/marc.1995.030160406",

language = "English",

volume = "16",

pages = "265--268",

journal = "Macromolecular Rapid Communications",

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T1 - Polymerizations of ethylene and styrene initiated with trisiloxane‐bridged dinuclear titanium metallocene/MMAO catalyst systems

AU - Lee, Dong‐ho ‐h

AU - Yoon, Keun‐byung ‐b

AU - Lee, Eok‐hyung ‐h

AU - Noh, Seok‐kyun ‐k

AU - Byun, Gyu‐gum ‐g

AU - Lee, Chul‐soo ‐s

PY - 1995/4

Y1 - 1995/4

N2 - Two kinds of the trisiloxane‐bridged dinuclear titanium metallocene‐type complexes were synthesized. They are monocyclopentadienyl and biscyclopentadienyl dinuclear titanocenes with trisiloxane bridges. The above complexes with modified methylaluminoxane (MMAO) cocatalyst initiate the polymerizations of ethylene and styrene to produce high‐density polyethylene and syndiotactic polystyrene. In addition, a copolymer of ethylene and styrene was obtained.

AB - Two kinds of the trisiloxane‐bridged dinuclear titanium metallocene‐type complexes were synthesized. They are monocyclopentadienyl and biscyclopentadienyl dinuclear titanocenes with trisiloxane bridges. The above complexes with modified methylaluminoxane (MMAO) cocatalyst initiate the polymerizations of ethylene and styrene to produce high‐density polyethylene and syndiotactic polystyrene. In addition, a copolymer of ethylene and styrene was obtained.

UR - http://www.scopus.com/inward/record.url?scp=84986760530&partnerID=8YFLogxK

U2 - 10.1002/marc.1995.030160406

DO - 10.1002/marc.1995.030160406

M3 - Article

AN - SCOPUS:84986760530

SN - 1022-1336

VL - 16

SP - 265

EP - 268

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 4

ER -

Polymerizations of ethylene and styrene initiated with trisiloxane‐bridged dinuclear titanium metallocene/MMAO catalyst systems

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