TY - JOUR
T1 - Porous carbon derived from covalent organic frameworks and relevant porous polymers
T2 - Preparation and application in adsorption and catalysis
AU - Ahmed, Imteaz
AU - Lee, Hye Jin
AU - Jhung, Sung Hwa
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2024/11/1
Y1 - 2024/11/1
N2 - Recent advancements in porous materials have significantly impacted energy storage/conversion and environmental remediation. Covalent organic framework (COF)-derived carbons (CDCs) have recently attracted significant scientific attention. COFs, formed by the ordered arrangement of organic linkers, create atomically precise porous frameworks but lose crystallinity upon high-temperature pyrolysis, resulting in mostly amorphous carbonaceous materials with high defect sites. Non-crystalline precursors, e.g. porous organic polymers (POPs) or covalent organic polymers (COPs), yield carbonaceous materials similar to CDCs. These materials can be synthesized using linkers similar to those in COFs. This review focuses on the preparation and applications of CDC materials in adsorption and catalysis, including those derived from POPs and COPs, while excluding those from conventional non-porous polymers. Future perspectives, together with the summary of the review, are also given to readers in the relevant fields.
AB - Recent advancements in porous materials have significantly impacted energy storage/conversion and environmental remediation. Covalent organic framework (COF)-derived carbons (CDCs) have recently attracted significant scientific attention. COFs, formed by the ordered arrangement of organic linkers, create atomically precise porous frameworks but lose crystallinity upon high-temperature pyrolysis, resulting in mostly amorphous carbonaceous materials with high defect sites. Non-crystalline precursors, e.g. porous organic polymers (POPs) or covalent organic polymers (COPs), yield carbonaceous materials similar to CDCs. These materials can be synthesized using linkers similar to those in COFs. This review focuses on the preparation and applications of CDC materials in adsorption and catalysis, including those derived from POPs and COPs, while excluding those from conventional non-porous polymers. Future perspectives, together with the summary of the review, are also given to readers in the relevant fields.
KW - Adsorptive remediation
KW - COF-derived carbon
KW - Covalent-organic framework
KW - Doped carbon
KW - Metal-free catalysis
UR - http://www.scopus.com/inward/record.url?scp=85204775078&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2024.156148
DO - 10.1016/j.cej.2024.156148
M3 - Review article
AN - SCOPUS:85204775078
SN - 1385-8947
VL - 499
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
M1 - 156148
ER -