Porous cobalt(II)-organic frameworks with corrugated walls: Structurally robust gas-sorption materials

Simon M. Humphrey; Jong San Chang; Sung Hwa Jhung; Ji Woong Yoon; Paul T. Wood

doi:10.1002/anie.200601627

Porous cobalt(II)-organic frameworks with corrugated walls: Structurally robust gas-sorption materials

Simon M. Humphrey, Jong San Chang, Sung Hwa Jhung, Ji Woong Yoon, Paul T. Wood

Research output: Contribution to journal › Article › peer-review

199 Scopus citations

Abstract

Resilient hosts: The porous coordination solids CUK-1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK-2 are synthesized from unsymmetrical ligands and Co^II ions. Even after the removal of co-crystallized guests, the host frameworks are exceptionally stable. CUK-1 shows a high capacity for H₂ adsorption and is one of very few materials capable of separating N₂ from O₂. (Figure Presented).

Original language	English
Pages (from-to)	272-275
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	1-2
DOIs	https://doi.org/10.1002/anie.200601627
State	Published - 2007

Keywords

Cobalt
Crystal engineering
Hydrogen storage
Hydrothermal synthesis
Microporous materials

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10.1002/anie.200601627

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abstract = "Resilient hosts: The porous coordination solids CUK-1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK-2 are synthesized from unsymmetrical ligands and CoII ions. Even after the removal of co-crystallized guests, the host frameworks are exceptionally stable. CUK-1 shows a high capacity for H2 adsorption and is one of very few materials capable of separating N2 from O2. (Figure Presented).",

keywords = "Cobalt, Crystal engineering, Hydrogen storage, Hydrothermal synthesis, Microporous materials",

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T1 - Porous cobalt(II)-organic frameworks with corrugated walls

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AU - Humphrey, Simon M.

AU - Chang, Jong San

AU - Jhung, Sung Hwa

AU - Yoon, Ji Woong

AU - Wood, Paul T.

PY - 2007

Y1 - 2007

N2 - Resilient hosts: The porous coordination solids CUK-1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK-2 are synthesized from unsymmetrical ligands and CoII ions. Even after the removal of co-crystallized guests, the host frameworks are exceptionally stable. CUK-1 shows a high capacity for H2 adsorption and is one of very few materials capable of separating N2 from O2. (Figure Presented).

AB - Resilient hosts: The porous coordination solids CUK-1 (see structure; Co purple, C gray, N blue, O red/pink) and CUK-2 are synthesized from unsymmetrical ligands and CoII ions. Even after the removal of co-crystallized guests, the host frameworks are exceptionally stable. CUK-1 shows a high capacity for H2 adsorption and is one of very few materials capable of separating N2 from O2. (Figure Presented).

KW - Cobalt

KW - Crystal engineering

KW - Hydrogen storage

KW - Hydrothermal synthesis

KW - Microporous materials

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U2 - 10.1002/anie.200601627

DO - 10.1002/anie.200601627

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SP - 272

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1-2

ER -

Porous cobalt(II)-organic frameworks with corrugated walls: Structurally robust gas-sorption materials

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Keywords

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