Possible scheme of synthesis - Assembling of fullerenes

F. N. Tomilin; P. V. Avramov; S. A. Varganov; A. A. Kuzubov; S. G. Ovchinnikov

doi:10.1134/1.1371387

Possible scheme of synthesis - Assembling of fullerenes

F. N. Tomilin, P. V. Avramov, S. A. Varganov, A. A. Kuzubov, S. G. Ovchinnikov

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14 Scopus citations

Abstract

A new scheme of fullerene formation is proposed on the basis of the similarity between the experimentally detected carbon structures. According to experimental data, the microclusters of C₂ and C₁₀ are synthesized first and then either an intermediate nucleus cluster or an obtainable lower fullerene is assembled from them. A high-symmetry fullerene can be assembled with a high probability from a nucleus cluster with a "good" symmetry. The atomic and electronic structures of molecules such as C₃₆, C₆₀, C₇₀, and C₇₆ are analyzed. For C₃₆, the NMR spectra are calculated and compared with the experimental data.

Original language	English
Pages (from-to)	973-981
Number of pages	9
Journal	Physics of the Solid State
Volume	43
Issue number	5
DOIs	https://doi.org/10.1134/1.1371387
State	Published - May 2001

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abstract = "A new scheme of fullerene formation is proposed on the basis of the similarity between the experimentally detected carbon structures. According to experimental data, the microclusters of C2 and C10 are synthesized first and then either an intermediate nucleus cluster or an obtainable lower fullerene is assembled from them. A high-symmetry fullerene can be assembled with a high probability from a nucleus cluster with a {"}good{"} symmetry. The atomic and electronic structures of molecules such as C36, C60, C70, and C76 are analyzed. For C36, the NMR spectra are calculated and compared with the experimental data.",

author = "Tomilin, {F. N.} and Avramov, {P. V.} and Varganov, {S. A.} and Kuzubov, {A. A.} and Ovchinnikov, {S. G.}",

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AU - Tomilin, F. N.

AU - Avramov, P. V.

AU - Varganov, S. A.

AU - Kuzubov, A. A.

AU - Ovchinnikov, S. G.

PY - 2001/5

Y1 - 2001/5

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AB - A new scheme of fullerene formation is proposed on the basis of the similarity between the experimentally detected carbon structures. According to experimental data, the microclusters of C2 and C10 are synthesized first and then either an intermediate nucleus cluster or an obtainable lower fullerene is assembled from them. A high-symmetry fullerene can be assembled with a high probability from a nucleus cluster with a "good" symmetry. The atomic and electronic structures of molecules such as C36, C60, C70, and C76 are analyzed. For C36, the NMR spectra are calculated and compared with the experimental data.

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VL - 43

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JO - Physics of the Solid State

JF - Physics of the Solid State

IS - 5

ER -

Possible scheme of synthesis - Assembling of fullerenes

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