Preparation and properties of propylene/POSS copolymer with rac-Et(Ind)2ZrCl2 catalyst

He xin Zhang; Young jun Shin; Keun byoung Yoon; Dong ho Lee

doi:10.1016/j.eurpolymj.2008.09.029

Preparation and properties of propylene/POSS copolymer with rac-Et(Ind)₂ZrCl₂ catalyst

He xin Zhang
, Young jun Shin
, Keun byoung Yoon
, Dong ho Lee

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

An organic-inorganic hybrid copolymer was prepared by using a C₂ symmetric ansa-metallocene catalyst in conjunction with modified methylaluminoxane (MMAO). Two kinds of monovinyl substituted polyhedral oligomeric silsesquioxane (POSS) monomers were used to copolymerize with propylene. A special experiment was carried out in order to confirm the purification of the copolymerization products. The unreacted monomer was completely removed by washing with an n-hexane/ethanol mixture. Thermal properties of the propylene/POSS copolymers exhibited improved thermal stability with higher degradation temperature and char yields, demonstrating that the inclusion of inorganic POSS nanoparticles made the organic polymer matrix more thermally robust.

Original language	English
Pages (from-to)	40-46
Number of pages	7
Journal	European Polymer Journal
Volume	45
Issue number	1
DOIs	https://doi.org/10.1016/j.eurpolymj.2008.09.029
State	Published - Jan 2009

Keywords

Copolymerization
Nanocomposite
Organic-inorganic hybrid copolymer
POSS

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10.1016/j.eurpolymj.2008.09.029

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title = "Preparation and properties of propylene/POSS copolymer with rac-Et(Ind)2ZrCl2 catalyst",

abstract = "An organic-inorganic hybrid copolymer was prepared by using a C2 symmetric ansa-metallocene catalyst in conjunction with modified methylaluminoxane (MMAO). Two kinds of monovinyl substituted polyhedral oligomeric silsesquioxane (POSS) monomers were used to copolymerize with propylene. A special experiment was carried out in order to confirm the purification of the copolymerization products. The unreacted monomer was completely removed by washing with an n-hexane/ethanol mixture. Thermal properties of the propylene/POSS copolymers exhibited improved thermal stability with higher degradation temperature and char yields, demonstrating that the inclusion of inorganic POSS nanoparticles made the organic polymer matrix more thermally robust.",

keywords = "Copolymerization, Nanocomposite, Organic-inorganic hybrid copolymer, POSS",

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AU - Zhang, He xin

AU - Shin, Young jun

AU - Yoon, Keun byoung

AU - Lee, Dong ho

PY - 2009/1

Y1 - 2009/1

N2 - An organic-inorganic hybrid copolymer was prepared by using a C2 symmetric ansa-metallocene catalyst in conjunction with modified methylaluminoxane (MMAO). Two kinds of monovinyl substituted polyhedral oligomeric silsesquioxane (POSS) monomers were used to copolymerize with propylene. A special experiment was carried out in order to confirm the purification of the copolymerization products. The unreacted monomer was completely removed by washing with an n-hexane/ethanol mixture. Thermal properties of the propylene/POSS copolymers exhibited improved thermal stability with higher degradation temperature and char yields, demonstrating that the inclusion of inorganic POSS nanoparticles made the organic polymer matrix more thermally robust.

AB - An organic-inorganic hybrid copolymer was prepared by using a C2 symmetric ansa-metallocene catalyst in conjunction with modified methylaluminoxane (MMAO). Two kinds of monovinyl substituted polyhedral oligomeric silsesquioxane (POSS) monomers were used to copolymerize with propylene. A special experiment was carried out in order to confirm the purification of the copolymerization products. The unreacted monomer was completely removed by washing with an n-hexane/ethanol mixture. Thermal properties of the propylene/POSS copolymers exhibited improved thermal stability with higher degradation temperature and char yields, demonstrating that the inclusion of inorganic POSS nanoparticles made the organic polymer matrix more thermally robust.

KW - Copolymerization

KW - Nanocomposite

KW - Organic-inorganic hybrid copolymer

KW - POSS

UR - https://www.scopus.com/pages/publications/58149163293

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DO - 10.1016/j.eurpolymj.2008.09.029

M3 - Article

AN - SCOPUS:58149163293

SN - 0014-3057

VL - 45

SP - 40

EP - 46

JO - European Polymer Journal

JF - European Polymer Journal

IS - 1

ER -

Preparation and properties of propylene/POSS copolymer with rac-Et(Ind)₂ZrCl₂ catalyst

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Keywords

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