Preparation of ethylene/polyhedral oligomeric silsesquioxane(POSS) copolymers with rac-Et(Ind)2ZrCl2/MMAO catalyst system

Dong Ho Lee; Keun Byoung Yoon; Myung Sung Jung; Jin Ki Sung; Seok Kyun Noh

doi:10.1016/s0167-2991(06)80434-9

Preparation of ethylene/polyhedral oligomeric silsesquioxane(POSS) copolymers with rac-Et(Ind)₂ZrCl₂/MMAO catalyst system

Dong Ho Lee, Keun Byoung Yoon, Myung Sung Jung, Jin Ki Sung, Seok Kyun Noh

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

To prepare the organic/inorganic hybrid copolymer, the norbornene derivatives of polyhedral oligomeric silsequioxane(POSS) such as norbornenylethyl-POSS (N-POSS) and dimethyl(norbornenylethyl)silyloxy-POSS(N-Si- POSS) had been copolymerized with ethylene by catalyst system of rac-Et(Ind)₂ZrCl₂/modified methylaluminoxane(MMAO). The catalytic activity decreased with the feed amount of POSS comonomer, and it was found that the reactivity of N-Si-POSS was larger than that of N-POSS. The unreacted POSS monomer was removed completely by washing the copolymerization product with n-hexane. The melting point of copolymer decreased with POSS content while the thermal stability, especially oxidation stability of copolymer was improved in a great extent relative to conventional polyethylene.

Original language	English
Pages (from-to)	53-58
Number of pages	6
Journal	Studies in Surface Science and Catalysis
Volume	161
DOIs	https://doi.org/10.1016/s0167-2991(06)80434-9
State	Published - 2006

Access to Document

10.1016/s0167-2991(06)80434-9

Cite this

@article{29f01fb95e6148e2a07b9e7a95b04b31,

title = "Preparation of ethylene/polyhedral oligomeric silsesquioxane(POSS) copolymers with rac-Et(Ind)2ZrCl2/MMAO catalyst system",

abstract = "To prepare the organic/inorganic hybrid copolymer, the norbornene derivatives of polyhedral oligomeric silsequioxane(POSS) such as norbornenylethyl-POSS (N-POSS) and dimethyl(norbornenylethyl)silyloxy-POSS(N-Si- POSS) had been copolymerized with ethylene by catalyst system of rac-Et(Ind)2ZrCl2/modified methylaluminoxane(MMAO). The catalytic activity decreased with the feed amount of POSS comonomer, and it was found that the reactivity of N-Si-POSS was larger than that of N-POSS. The unreacted POSS monomer was removed completely by washing the copolymerization product with n-hexane. The melting point of copolymer decreased with POSS content while the thermal stability, especially oxidation stability of copolymer was improved in a great extent relative to conventional polyethylene.",

author = "Lee, {Dong Ho} and Yoon, {Keun Byoung} and Jung, {Myung Sung} and Sung, {Jin Ki} and Noh, {Seok Kyun}",

year = "2006",

doi = "10.1016/s0167-2991(06)80434-9",

language = "English",

volume = "161",

pages = "53--58",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

}

TY - JOUR

T1 - Preparation of ethylene/polyhedral oligomeric silsesquioxane(POSS) copolymers with rac-Et(Ind)2ZrCl2/MMAO catalyst system

AU - Lee, Dong Ho

AU - Yoon, Keun Byoung

AU - Jung, Myung Sung

AU - Sung, Jin Ki

AU - Noh, Seok Kyun

PY - 2006

Y1 - 2006

N2 - To prepare the organic/inorganic hybrid copolymer, the norbornene derivatives of polyhedral oligomeric silsequioxane(POSS) such as norbornenylethyl-POSS (N-POSS) and dimethyl(norbornenylethyl)silyloxy-POSS(N-Si- POSS) had been copolymerized with ethylene by catalyst system of rac-Et(Ind)2ZrCl2/modified methylaluminoxane(MMAO). The catalytic activity decreased with the feed amount of POSS comonomer, and it was found that the reactivity of N-Si-POSS was larger than that of N-POSS. The unreacted POSS monomer was removed completely by washing the copolymerization product with n-hexane. The melting point of copolymer decreased with POSS content while the thermal stability, especially oxidation stability of copolymer was improved in a great extent relative to conventional polyethylene.

AB - To prepare the organic/inorganic hybrid copolymer, the norbornene derivatives of polyhedral oligomeric silsequioxane(POSS) such as norbornenylethyl-POSS (N-POSS) and dimethyl(norbornenylethyl)silyloxy-POSS(N-Si- POSS) had been copolymerized with ethylene by catalyst system of rac-Et(Ind)2ZrCl2/modified methylaluminoxane(MMAO). The catalytic activity decreased with the feed amount of POSS comonomer, and it was found that the reactivity of N-Si-POSS was larger than that of N-POSS. The unreacted POSS monomer was removed completely by washing the copolymerization product with n-hexane. The melting point of copolymer decreased with POSS content while the thermal stability, especially oxidation stability of copolymer was improved in a great extent relative to conventional polyethylene.

UR - http://www.scopus.com/inward/record.url?scp=33845651395&partnerID=8YFLogxK

U2 - 10.1016/s0167-2991(06)80434-9

DO - 10.1016/s0167-2991(06)80434-9

M3 - Article

AN - SCOPUS:33845651395

SN - 0167-2991

VL - 161

SP - 53

EP - 58

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Preparation of ethylene/polyhedral oligomeric silsesquioxane(POSS) copolymers with rac-Et(Ind)₂ZrCl₂/MMAO catalyst system

Abstract

Access to Document

Other files and links

Fingerprint

Cite this