Preparation of Thiophene-Coordinated Ruthenium Complexes for Nonlinear Optics

In Su Lee; Dae Seung Choi; Dong Mok Shin; Young Keun Chung; Cheol Ho Choi

doi:10.1021/om034324i

Preparation of Thiophene-Coordinated Ruthenium Complexes for Nonlinear Optics

In Su Lee, Dae Seung Choi, Dong Mok Shin, Young Keun Chung, Cheol Ho Choi

Seoul National University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The new organometallic compounds [{(E)-2-SC₄H ₃CH=CHC₆H₄-X-p}Ru(C₆Me ₆)][CF₃SO₃]₂ (X = MeO (1), Me (2), H (3), Br (4), NO₂ (5)), bearing a (thiophene)Ru(C₆Me ₆)²⁺ fragment in the end group, have been prepared for nonlinear optical chromophores, and their hyperpolarizabilities have been measured by the HRS method. The static hyperpolarizability (β₀) values of the complexes increase as the electron-acceptor power of the substituent X increases (MeO < Me < H < Br < NO₂). Replacement of hexamethylbenzene with pentamethylcyclopentadienyl resulted in [{(E)-2-SC₄H₃CH=CHC₆H₄-NO ₂-p}]Ru(C₅Me₅)]CF₃SO₃ (7), showing a significant increase in the hyperpolarizability. The substituent effects on β₀ were studied by time-dependent DFT calculations.

Original language	English
Pages (from-to)	1875-1879
Number of pages	5
Journal	Organometallics
Volume	23
Issue number	8
DOIs	https://doi.org/10.1021/om034324i
State	Published - 12 Apr 2004

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@article{894ba808f7904dfd82e28ed7e8c3e3e4,

title = "Preparation of Thiophene-Coordinated Ruthenium Complexes for Nonlinear Optics",

abstract = "The new organometallic compounds [{(E)-2-SC4H 3CH=CHC6H4-X-p}Ru(C6Me 6)][CF3SO3]2 (X = MeO (1), Me (2), H (3), Br (4), NO2 (5)), bearing a (thiophene)Ru(C6Me 6)2+ fragment in the end group, have been prepared for nonlinear optical chromophores, and their hyperpolarizabilities have been measured by the HRS method. The static hyperpolarizability (β0) values of the complexes increase as the electron-acceptor power of the substituent X increases (MeO < Me < H < Br < NO2). Replacement of hexamethylbenzene with pentamethylcyclopentadienyl resulted in [{(E)-2-SC4H3CH=CHC6H4-NO 2-p}]Ru(C5Me5)]CF3SO3 (7), showing a significant increase in the hyperpolarizability. The substituent effects on β0 were studied by time-dependent DFT calculations.",

author = "Lee, {In Su} and Choi, {Dae Seung} and Shin, {Dong Mok} and Chung, {Young Keun} and Choi, {Cheol Ho}",

year = "2004",

month = apr,

day = "12",

doi = "10.1021/om034324i",

language = "English",

volume = "23",

pages = "1875--1879",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Preparation of Thiophene-Coordinated Ruthenium Complexes for Nonlinear Optics

AU - Lee, In Su

AU - Choi, Dae Seung

AU - Shin, Dong Mok

AU - Chung, Young Keun

AU - Choi, Cheol Ho

PY - 2004/4/12

Y1 - 2004/4/12

N2 - The new organometallic compounds [{(E)-2-SC4H 3CH=CHC6H4-X-p}Ru(C6Me 6)][CF3SO3]2 (X = MeO (1), Me (2), H (3), Br (4), NO2 (5)), bearing a (thiophene)Ru(C6Me 6)2+ fragment in the end group, have been prepared for nonlinear optical chromophores, and their hyperpolarizabilities have been measured by the HRS method. The static hyperpolarizability (β0) values of the complexes increase as the electron-acceptor power of the substituent X increases (MeO < Me < H < Br < NO2). Replacement of hexamethylbenzene with pentamethylcyclopentadienyl resulted in [{(E)-2-SC4H3CH=CHC6H4-NO 2-p}]Ru(C5Me5)]CF3SO3 (7), showing a significant increase in the hyperpolarizability. The substituent effects on β0 were studied by time-dependent DFT calculations.

AB - The new organometallic compounds [{(E)-2-SC4H 3CH=CHC6H4-X-p}Ru(C6Me 6)][CF3SO3]2 (X = MeO (1), Me (2), H (3), Br (4), NO2 (5)), bearing a (thiophene)Ru(C6Me 6)2+ fragment in the end group, have been prepared for nonlinear optical chromophores, and their hyperpolarizabilities have been measured by the HRS method. The static hyperpolarizability (β0) values of the complexes increase as the electron-acceptor power of the substituent X increases (MeO < Me < H < Br < NO2). Replacement of hexamethylbenzene with pentamethylcyclopentadienyl resulted in [{(E)-2-SC4H3CH=CHC6H4-NO 2-p}]Ru(C5Me5)]CF3SO3 (7), showing a significant increase in the hyperpolarizability. The substituent effects on β0 were studied by time-dependent DFT calculations.

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U2 - 10.1021/om034324i

DO - 10.1021/om034324i

M3 - Article

AN - SCOPUS:2342443771

SN - 0276-7333

VL - 23

SP - 1875

EP - 1879

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Preparation of Thiophene-Coordinated Ruthenium Complexes for Nonlinear Optics

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