Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)

Shohei Saito; Jae Yoon Shin; Jong Min Lim; Kil Suk Kim; Dongho Kim; Atsuhiro Osuka

doi:10.1002/anie.200804457

Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)

Shohei Saito
, Jae Yoon Shin
, Jong Min Lim
, Kil Suk Kim
, Dongho Kim
, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).

Original language	English
Pages (from-to)	9657-9660
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200804457
State	Published - 1 Dec 2008

Keywords

Aromaticity
Heptaphyrins
Möbius aromaticity
Porphyrinoids
Two-photon absorption

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10.1002/anie.200804457

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title = "Protonation-triggered conformational changes to M{\"o}bius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)",

abstract = "Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic M{\"o}bius structures (see picture), even at room temperature. (Figure Presented).",

keywords = "Aromaticity, Heptaphyrins, M{\"o}bius aromaticity, Porphyrinoids, Two-photon absorption",

author = "Shohei Saito and Shin, \{Jae Yoon\} and Lim, \{Jong Min\} and Kim, \{Kil Suk\} and Dongho Kim and Atsuhiro Osuka",

year = "2008",

month = dec,

day = "1",

doi = "10.1002/anie.200804457",

language = "English",

volume = "47",

pages = "9657--9660",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)

AU - Saito, Shohei

AU - Shin, Jae Yoon

AU - Lim, Jong Min

AU - Kim, Kil Suk

AU - Kim, Dongho

AU - Osuka, Atsuhiro

PY - 2008/12/1

Y1 - 2008/12/1

N2 - Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).

AB - Switching Aromaticity: Conformations of [32]heptaphyrins (1.1.1.1.1.1.1) are dependent upon meso-aryl substituents, solvents, temperature, and protonation. Particularly, protonation of meso-pentafluorophenyl-substituted [32]heptaphyrin triggers conformational changes to form twisted aromatic Möbius structures (see picture), even at room temperature. (Figure Presented).

KW - Aromaticity

KW - Heptaphyrins

KW - Möbius aromaticity

KW - Porphyrinoids

KW - Two-photon absorption

UR - https://www.scopus.com/pages/publications/57049099788

U2 - 10.1002/anie.200804457

DO - 10.1002/anie.200804457

M3 - Article

AN - SCOPUS:57049099788

SN - 1433-7851

VL - 47

SP - 9657

EP - 9660

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Protonation-triggered conformational changes to Möbius aromatic [32]heptaphyrins(1.1.1.1.1.1.1)

Abstract

Keywords

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