PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Sun Jong Lee; Ki Nam Oh; Jung Min Lee; Jung Hyun Kim; In Woo Cheong

doi:10.1166/jnn.2010.2951

PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Sun Jong Lee
, Ki Nam Oh
, Jung Min Lee
, Jung Hyun Kim
, In Woo Cheong

Yonsei University

Research output: Contribution to journal › Article › peer-review

Abstract

Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe ³⁺-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI ₃/H ₂0 ₂ (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI ₃. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H ₂0 ₂ increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

Original language	English
Pages (from-to)	6944-6947
Number of pages	4
Journal	Journal of Nanoscience and Nanotechnology
Volume	10
Issue number	10
DOIs	https://doi.org/10.1166/jnn.2010.2951
State	Published - Oct 2010

Keywords

Conductivity
Film Formation
Nanoparticles
Polythiophene
Transparency

Access to Document

10.1166/jnn.2010.2951

Cite this

@article{a49c06b437ba432b811ca96d8be6140d,

title = "PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films",

abstract = "Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95\%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.",

keywords = "Conductivity, Film Formation, Nanoparticles, Polythiophene, Transparency",

author = "Lee, \{Sun Jong\} and Oh, \{Ki Nam\} and Lee, \{Jung Min\} and Kim, \{Jung Hyun\} and Cheong, \{In Woo\}",

year = "2010",

month = oct,

doi = "10.1166/jnn.2010.2951",

language = "English",

volume = "10",

pages = "6944--6947",

journal = "Journal of Nanoscience and Nanotechnology",

issn = "1533-4880",

publisher = "American Scientific Publishers",

number = "10",

}

TY - JOUR

T1 - PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

AU - Lee, Sun Jong

AU - Oh, Ki Nam

AU - Lee, Jung Min

AU - Kim, Jung Hyun

AU - Cheong, In Woo

PY - 2010/10

Y1 - 2010/10

N2 - Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

AB - Polythiophene/poly(sodium 4-styrene sulfonate) (PT/PSS) composite nanoparticles having different particle size were prepared by Fe 3+-catalyzed oxidative polymerization in aqueous medium. This facile method includes a FeCI 3/H 20 2 (catalyst/oxidant) combination system, which guarantees a high conversion (more than 95%) of thiophene monomers in various concentration of poly(styrene sulfonate) (PSS) with only a trace of FeCI 3. Particle size of PT/PSS composite nanoparticles decreased from 134 nm to 26 nm as the concentration of PSS and H 20 2 increased, and which was confirmed by SEM and CHDF analyses. The poly(ethylene terephthalate) (PET) film coated with PT/PSS was transparent and showed a high conductivity in a dried state. The sheet resistivity decreased as the ratio of PT to PSS increased. Photoluminescence property of the PT/PSS composite nanoparticles was also investigated.

KW - Conductivity

KW - Film Formation

KW - Nanoparticles

KW - Polythiophene

KW - Transparency

UR - https://www.scopus.com/pages/publications/79955526644

U2 - 10.1166/jnn.2010.2951

DO - 10.1166/jnn.2010.2951

M3 - Article

AN - SCOPUS:79955526644

SN - 1533-4880

VL - 10

SP - 6944

EP - 6947

JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 10

ER -

PSS resin-fortified polythiophene nanoparticles for highly transparent conducting films

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this