Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm3+

P. Meejitpaisan; S. Insiripong; C. Kedkaew; H. J. Kim; J. Kaewkhao

doi:10.1016/j.radphyschem.2016.01.043

Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm³⁺

P. Meejitpaisan
, S. Insiripong
, C. Kedkaew
, H. J. Kim
, J. Kaewkhao

King Mongkut's University of Technology Thonburi
Muban Chom Bueng Rajabhat University
Nakhon Pathom Rajabhat University

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Sm³⁺-doped gadolinium calcium phosphate oxyfluoride glasses have been synthesized and investigated their optical, photo and radioluminescence properties. The glasses were prepared by melt quenching technique at 1400 °C. The characteristic absorption bands of Sm³⁺ ions originating from the ⁶H_5/2 ground state and occurring absorbed photon in visible light (VIS) and near-infrared (NIR) region with clearly observed from absorption spectra. From the photoluminescence (PL), the glasses showed the emission at 561 (⁴G_5/2→⁶H_5/2), 598 (⁴G_5/2→⁶H_7/2), 644 (⁴G_5/2→⁶H_9/2) and 705 nm (⁴G_5/2→⁶H_11/2). The radioluminescence (RL), emission spectra were corresponding to those from PL measurements. From RL measurement, the integral scintillation efficiency of developed glass was determined at 43% when compared with BGO crystal.

Original language	English
Pages (from-to)	62-67
Number of pages	6
Journal	Radiation Physics and Chemistry
Volume	137
DOIs	https://doi.org/10.1016/j.radphyschem.2016.01.043
State	Published - Aug 2017

Keywords

Optical
Oxyfluoride
Phosphate
Radioluminescence

Access to Document

10.1016/j.radphyschem.2016.01.043

Cite this

@article{5d873657ea2147fd81c811e9a85e913d,

title = "Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm3+",

abstract = "Sm3+-doped gadolinium calcium phosphate oxyfluoride glasses have been synthesized and investigated their optical, photo and radioluminescence properties. The glasses were prepared by melt quenching technique at 1400 °C. The characteristic absorption bands of Sm3+ ions originating from the 6H5/2 ground state and occurring absorbed photon in visible light (VIS) and near-infrared (NIR) region with clearly observed from absorption spectra. From the photoluminescence (PL), the glasses showed the emission at 561 (4G5/2→6H5/2), 598 (4G5/2→6H7/2), 644 (4G5/2→6H9/2) and 705 nm (4G5/2→6H11/2). The radioluminescence (RL), emission spectra were corresponding to those from PL measurements. From RL measurement, the integral scintillation efficiency of developed glass was determined at 43\% when compared with BGO crystal.",

keywords = "Optical, Oxyfluoride, Phosphate, Radioluminescence",

author = "P. Meejitpaisan and S. Insiripong and C. Kedkaew and Kim, \{H. J.\} and J. Kaewkhao",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd",

year = "2017",

month = aug,

doi = "10.1016/j.radphyschem.2016.01.043",

language = "English",

volume = "137",

pages = "62--67",

journal = "Radiation Physics and Chemistry",

issn = "0969-806X",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm3+

AU - Meejitpaisan, P.

AU - Insiripong, S.

AU - Kedkaew, C.

AU - Kim, H. J.

AU - Kaewkhao, J.

PY - 2017/8

Y1 - 2017/8

N2 - Sm3+-doped gadolinium calcium phosphate oxyfluoride glasses have been synthesized and investigated their optical, photo and radioluminescence properties. The glasses were prepared by melt quenching technique at 1400 °C. The characteristic absorption bands of Sm3+ ions originating from the 6H5/2 ground state and occurring absorbed photon in visible light (VIS) and near-infrared (NIR) region with clearly observed from absorption spectra. From the photoluminescence (PL), the glasses showed the emission at 561 (4G5/2→6H5/2), 598 (4G5/2→6H7/2), 644 (4G5/2→6H9/2) and 705 nm (4G5/2→6H11/2). The radioluminescence (RL), emission spectra were corresponding to those from PL measurements. From RL measurement, the integral scintillation efficiency of developed glass was determined at 43% when compared with BGO crystal.

AB - Sm3+-doped gadolinium calcium phosphate oxyfluoride glasses have been synthesized and investigated their optical, photo and radioluminescence properties. The glasses were prepared by melt quenching technique at 1400 °C. The characteristic absorption bands of Sm3+ ions originating from the 6H5/2 ground state and occurring absorbed photon in visible light (VIS) and near-infrared (NIR) region with clearly observed from absorption spectra. From the photoluminescence (PL), the glasses showed the emission at 561 (4G5/2→6H5/2), 598 (4G5/2→6H7/2), 644 (4G5/2→6H9/2) and 705 nm (4G5/2→6H11/2). The radioluminescence (RL), emission spectra were corresponding to those from PL measurements. From RL measurement, the integral scintillation efficiency of developed glass was determined at 43% when compared with BGO crystal.

KW - Optical

KW - Oxyfluoride

KW - Phosphate

KW - Radioluminescence

UR - https://www.scopus.com/pages/publications/84957088895

U2 - 10.1016/j.radphyschem.2016.01.043

DO - 10.1016/j.radphyschem.2016.01.043

M3 - Article

AN - SCOPUS:84957088895

SN - 0969-806X

VL - 137

SP - 62

EP - 67

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

ER -

Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm³⁺

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this