Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal

Sunghwan Park; Albert S. Lee; Yu Seong Do; Seung Sang Hwang; Young Moo Lee; Jung Hyun Lee; Jong Suk Lee

doi:10.1039/c5cc06269a

Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO₂ removal

Sunghwan Park
, Albert S. Lee
, Yu Seong Do
, Seung Sang Hwang
, Young Moo Lee
, Jung Hyun Lee
, Jong Suk Lee

Department of Energy Chemical Engineering

Korea Institute of Science and Technology
Hanyang University
Korea University

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO₂/H₂ and CO₂/N₂ separation under single as well as mixed gas conditions.

Original language	English
Pages (from-to)	15308-15311
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	83
DOIs	https://doi.org/10.1039/c5cc06269a
State	Published - 24 Aug 2015

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10.1039/c5cc06269a

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title = "Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal",

abstract = "Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H2 and CO2/N2 separation under single as well as mixed gas conditions.",

author = "Sunghwan Park and Lee, \{Albert S.\} and Do, \{Yu Seong\} and Hwang, \{Seung Sang\} and Lee, \{Young Moo\} and Lee, \{Jung Hyun\} and Lee, \{Jong Suk\}",

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T1 - Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal

AU - Park, Sunghwan

AU - Lee, Albert S.

AU - Do, Yu Seong

AU - Hwang, Seung Sang

AU - Lee, Young Moo

AU - Lee, Jung Hyun

AU - Lee, Jong Suk

PY - 2015/8/24

Y1 - 2015/8/24

N2 - Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H2 and CO2/N2 separation under single as well as mixed gas conditions.

AB - Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H2 and CO2/N2 separation under single as well as mixed gas conditions.

UR - https://www.scopus.com/pages/publications/84943755850

U2 - 10.1039/c5cc06269a

DO - 10.1039/c5cc06269a

M3 - Article

C2 - 26340230

AN - SCOPUS:84943755850

SN - 1359-7345

VL - 51

SP - 15308

EP - 15311

JO - Chemical Communications

JF - Chemical Communications

IS - 83

ER -

Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO₂ removal

Abstract

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