Reduction of nitroarenes followed by propanol group transfer from tris(3-hydroxypropyl)- amine and cyclization leading to quinolines under heterogeneous Pd-C catalysis

Chan Sik Cho; Tae Gyun Kim; Nam Sik Yoon

doi:10.1002/aoc.1596

Reduction of nitroarenes followed by propanol group transfer from tris(3-hydroxypropyl)- amine and cyclization leading to quinolines under heterogeneous Pd-C catalysis

Chan Sik Cho, Tae Gyun Kim, Nam Sik Yoon

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Nitroarenes having electron-donating or -withdrawing substituents are reduced to anilines and cyclized with tris(3- hydroxypropyl)amine in the presence of a catalytic amount of Pd-C along with tin(II) chloride and isopropanol in dioxane-H₂O medium to give the corresponding quinolines in good to excellent yields.

Original language	English
Pages (from-to)	291-293
Number of pages	3
Journal	Applied Organometallic Chemistry
Volume	24
Issue number	4
DOIs	https://doi.org/10.1002/aoc.1596
State	Published - Apr 2010

Keywords

Amine exchange reaction
Cyclization
Nitroarenes
Palladium catalyst
Quinolines

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10.1002/aoc.1596

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abstract = "Nitroarenes having electron-donating or -withdrawing substituents are reduced to anilines and cyclized with tris(3- hydroxypropyl)amine in the presence of a catalytic amount of Pd-C along with tin(II) chloride and isopropanol in dioxane-H2O medium to give the corresponding quinolines in good to excellent yields.",

keywords = "Amine exchange reaction, Cyclization, Nitroarenes, Palladium catalyst, Quinolines",

author = "Cho, {Chan Sik} and Kim, {Tae Gyun} and Yoon, {Nam Sik}",

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AU - Cho, Chan Sik

AU - Kim, Tae Gyun

AU - Yoon, Nam Sik

PY - 2010/4

Y1 - 2010/4

N2 - Nitroarenes having electron-donating or -withdrawing substituents are reduced to anilines and cyclized with tris(3- hydroxypropyl)amine in the presence of a catalytic amount of Pd-C along with tin(II) chloride and isopropanol in dioxane-H2O medium to give the corresponding quinolines in good to excellent yields.

AB - Nitroarenes having electron-donating or -withdrawing substituents are reduced to anilines and cyclized with tris(3- hydroxypropyl)amine in the presence of a catalytic amount of Pd-C along with tin(II) chloride and isopropanol in dioxane-H2O medium to give the corresponding quinolines in good to excellent yields.

KW - Amine exchange reaction

KW - Cyclization

KW - Nitroarenes

KW - Palladium catalyst

KW - Quinolines

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U2 - 10.1002/aoc.1596

DO - 10.1002/aoc.1596

M3 - Article

AN - SCOPUS:77949701857

SN - 0268-2605

VL - 24

SP - 291

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JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

IS - 4

ER -

Reduction of nitroarenes followed by propanol group transfer from tris(3-hydroxypropyl)- amine and cyclization leading to quinolines under heterogeneous Pd-C catalysis

Abstract

Keywords

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