Room-temperature spin crossover observed for [(TPyA)Fe II(DBQ2-)FeIITPyA]2+ [TPyA = tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]

Sik Min Kil; Antonio DiPasquale; Arnold L. Rheingold; Joel S. Miller

doi:10.1021/ic062400e

Room-temperature spin crossover observed for [(TPyA)Fe ^II(DBQ^2-)Fe^IITPyA]²⁺ [TPyA = tris(2-pyridylmethyl)amine; DBQ^2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]

Sik Min Kil
, Antonio DiPasquale
, Arnold L. Rheingold
, Joel S. Miller

Department of Chemical Science Education

University of California at San Diego
University of Utah

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

Dinuclear [(TPyA)Fe^II(DBQ^2-)Fe^II(TPyA)] (BF₄)₂ possesses extensive π-π interactions between the Fe^II dimers that give rise to a two-dimensional supramolecular sheet structure. The magnetic susceptibility shows a room-temperature spin-crossover behavior; however, thermal hysteresis is not observed.

Original language	English
Pages (from-to)	1048-1050
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	4
DOIs	https://doi.org/10.1021/ic062400e
State	Published - 19 Feb 2007

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10.1021/ic062400e

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title = "Room-temperature spin crossover observed for [(TPyA)Fe II(DBQ2-)FeIITPyA]2+ [TPyA = tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]",

abstract = "Dinuclear [(TPyA)FeII(DBQ2-)FeII(TPyA)] (BF4)2 possesses extensive π-π interactions between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure. The magnetic susceptibility shows a room-temperature spin-crossover behavior; however, thermal hysteresis is not observed.",

author = "Kil, \{Sik Min\} and Antonio DiPasquale and Rheingold, \{Arnold L.\} and Miller, \{Joel S.\}",

year = "2007",

month = feb,

day = "19",

doi = "10.1021/ic062400e",

language = "English",

volume = "46",

pages = "1048--1050",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "4",

}

Room-temperature spin crossover observed for [(TPyA)Fe ^II(DBQ^2-)Fe^IITPyA]²⁺ [TPyA = tris(2-pyridylmethyl)amine; DBQ^2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]. / Kil, Sik Min; DiPasquale, Antonio; Rheingold, Arnold L. et al.
In: Inorganic Chemistry, Vol. 46, No. 4, 19.02.2007, p. 1048-1050.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Room-temperature spin crossover observed for [(TPyA)Fe II(DBQ2-)FeIITPyA]2+ [TPyA = tris(2-pyridylmethyl)amine; DBQ2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]

AU - Kil, Sik Min

AU - DiPasquale, Antonio

AU - Rheingold, Arnold L.

AU - Miller, Joel S.

PY - 2007/2/19

Y1 - 2007/2/19

N2 - Dinuclear [(TPyA)FeII(DBQ2-)FeII(TPyA)] (BF4)2 possesses extensive π-π interactions between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure. The magnetic susceptibility shows a room-temperature spin-crossover behavior; however, thermal hysteresis is not observed.

AB - Dinuclear [(TPyA)FeII(DBQ2-)FeII(TPyA)] (BF4)2 possesses extensive π-π interactions between the FeII dimers that give rise to a two-dimensional supramolecular sheet structure. The magnetic susceptibility shows a room-temperature spin-crossover behavior; however, thermal hysteresis is not observed.

UR - https://www.scopus.com/pages/publications/33947147332

U2 - 10.1021/ic062400e

DO - 10.1021/ic062400e

M3 - Article

AN - SCOPUS:33947147332

SN - 0020-1669

VL - 46

SP - 1048

EP - 1050

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Room-temperature spin crossover observed for [(TPyA)Fe ^II(DBQ^2-)Fe^IITPyA]²⁺ [TPyA = tris(2-pyridylmethyl)amine; DBQ^2- = 2,5-Di-tert-butyl-3,6-dihydroxy- 1,4-benzoquinonate]

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