Ruthenium-catalysed selective N-monoalkylation of anilines with tetraalkyl-ammonium halides

Chan Sik Cho; Joon Seok Kim; Hun Seol Kim; Tae Jeong Kim; Sang Chul Shim

doi:10.1081/SCC-100108229

Ruthenium-catalysed selective N-monoalkylation of anilines with tetraalkyl-ammonium halides

Chan Sik Cho, Joon Seok Kim, Hun Seol Kim, Tae Jeong Kim, Sang Chul Shim

Department of Applied Chemistry

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Anilines react with an array of tetraalkylammonium halides in the presence of a catalytic amount of a ruthenium catalyst together with SnCl₂·2H₂O in dioxane at 180°C to afford selectively N-monoalkylanilines in good yields.

Original language	English
Pages (from-to)	3791-3797
Number of pages	7
Journal	Synthetic Communications
Volume	31
Issue number	24
DOIs	https://doi.org/10.1081/SCC-100108229
State	Published - 1 Jan 2001

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title = "Ruthenium-catalysed selective N-monoalkylation of anilines with tetraalkyl-ammonium halides",

abstract = "Anilines react with an array of tetraalkylammonium halides in the presence of a catalytic amount of a ruthenium catalyst together with SnCl2·2H2O in dioxane at 180°C to afford selectively N-monoalkylanilines in good yields.",

author = "Cho, {Chan Sik} and Kim, {Joon Seok} and Kim, {Hun Seol} and Kim, {Tae Jeong} and Shim, {Sang Chul}",

year = "2001",

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doi = "10.1081/SCC-100108229",

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T1 - Ruthenium-catalysed selective N-monoalkylation of anilines with tetraalkyl-ammonium halides

AU - Cho, Chan Sik

AU - Kim, Joon Seok

AU - Kim, Hun Seol

AU - Kim, Tae Jeong

AU - Shim, Sang Chul

PY - 2001/1/1

Y1 - 2001/1/1

N2 - Anilines react with an array of tetraalkylammonium halides in the presence of a catalytic amount of a ruthenium catalyst together with SnCl2·2H2O in dioxane at 180°C to afford selectively N-monoalkylanilines in good yields.

AB - Anilines react with an array of tetraalkylammonium halides in the presence of a catalytic amount of a ruthenium catalyst together with SnCl2·2H2O in dioxane at 180°C to afford selectively N-monoalkylanilines in good yields.

UR - http://www.scopus.com/inward/record.url?scp=0035207496&partnerID=8YFLogxK

U2 - 10.1081/SCC-100108229

DO - 10.1081/SCC-100108229

M3 - Article

AN - SCOPUS:0035207496

SN - 0039-7911

VL - 31

SP - 3791

EP - 3797

JO - Synthetic Communications

JF - Synthetic Communications

IS - 24

ER -

Ruthenium-catalysed selective N-monoalkylation of anilines with tetraalkyl-ammonium halides

Abstract

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