Abstract
A two-dimensional chiral open framework, [Ni(LR,R)] 3[C6H3(COO)3]2· 12H2O·CH3CN (3), is prepared from a nickel(II) macrocyclic complex with chiral pendants and benzenetricarboxylate in MeCN/H2O and characterized [LR,R = 1,8-bis[(R)-α- methylbenzyl]-1,3,6,8,10,13-hexaazacyclotetradecane]. The open framework shows selective chiral recognition by interactions between the solid 3 and rac-1,1′-bi-2-naphthol.
Original language | English |
---|---|
Pages (from-to) | 7232-7234 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 49 |
Issue number | 16 |
DOIs | |
State | Published - 16 Aug 2010 |