Self-assembly and chiral recognition of a two-dimensional coordination polymer from a chiral nickel(II) macrocyclic complex and trimesic acid

Jae Jeong Ryoo, Jong Won Shin, Hwan Seok Dho, Kil Sik Min

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

A two-dimensional chiral open framework, [Ni(LR,R)] 3[C6H3(COO)3]2· 12H2O·CH3CN (3), is prepared from a nickel(II) macrocyclic complex with chiral pendants and benzenetricarboxylate in MeCN/H2O and characterized [LR,R = 1,8-bis[(R)-α- methylbenzyl]-1,3,6,8,10,13-hexaazacyclotetradecane]. The open framework shows selective chiral recognition by interactions between the solid 3 and rac-1,1′-bi-2-naphthol.

Original languageEnglish
Pages (from-to)7232-7234
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number16
DOIs
StatePublished - 16 Aug 2010

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