Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid

Ji Hye Park; Ah Rim Jeong; Jong Won Shin; Maeng Jun Jeong; Chan Sik Cho; Kil Sik Min

doi:10.1016/j.inoche.2015.04.023

Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid

Ji Hye Park
, Ah Rim Jeong
, Jong Won Shin
, Maeng Jun Jeong
, Chan Sik Cho
, Kil Sik Min

Kyungpook National University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Abstract Reaction of the nickel(II) macrocyclic complex 1 including pendant pentyl groups in MeCN/H₂O mixed solvent with deprotonated cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTC^{3 -}) resulted in two-dimensional (2-D) coordination polymer [Ni(C₁₈H₄₂N₆)]₃[C₆H₉(COO)₃]₂·6H₂O·6CH₃CN (2). The crystal structure of 2 indicates that each nickel(II) macrocyclic unit binds two CTC^{3 -} ions in trans position and each CTC^{3 -} ion coordinates three nickel(II) macrocyclic complexes to form a 2-D layer with hexagonal motif. The dried solid of 2 differentiates MeOH, EtOH, and PhOH in toluene solvent with the K_f values of 1.38, 2.11, and 6.68 M^{- 1}, respectively.

Original language	English
Article number	5977
Pages (from-to)	44-46
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	57
DOIs	https://doi.org/10.1016/j.inoche.2015.04.023
State	Published - 1 Jul 2015

Keywords

Coordination polymer
Crystal structure
Guest binding
Macrocyclic ligand
Nickel(II)

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@article{5054d2be57f34bc78129699684f232ae,

title = "Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid",

abstract = "Abstract Reaction of the nickel(II) macrocyclic complex 1 including pendant pentyl groups in MeCN/H2O mixed solvent with deprotonated cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTC3 -) resulted in two-dimensional (2-D) coordination polymer [Ni(C18H42N6)]3[C6H9(COO)3]2·6H2O·6CH3CN (2). The crystal structure of 2 indicates that each nickel(II) macrocyclic unit binds two CTC3 - ions in trans position and each CTC3 - ion coordinates three nickel(II) macrocyclic complexes to form a 2-D layer with hexagonal motif. The dried solid of 2 differentiates MeOH, EtOH, and PhOH in toluene solvent with the Kf values of 1.38, 2.11, and 6.68 M- 1, respectively.",

keywords = "Coordination polymer, Crystal structure, Guest binding, Macrocyclic ligand, Nickel(II)",

author = "Park, \{Ji Hye\} and Jeong, \{Ah Rim\} and Shin, \{Jong Won\} and Jeong, \{Maeng Jun\} and Cho, \{Chan Sik\} and Min, \{Kil Sik\}",

year = "2015",

month = jul,

day = "1",

doi = "10.1016/j.inoche.2015.04.023",

language = "English",

volume = "57",

pages = "44--46",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid

AU - Park, Ji Hye

AU - Jeong, Ah Rim

AU - Shin, Jong Won

AU - Jeong, Maeng Jun

AU - Cho, Chan Sik

AU - Min, Kil Sik

PY - 2015/7/1

Y1 - 2015/7/1

N2 - Abstract Reaction of the nickel(II) macrocyclic complex 1 including pendant pentyl groups in MeCN/H2O mixed solvent with deprotonated cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTC3 -) resulted in two-dimensional (2-D) coordination polymer [Ni(C18H42N6)]3[C6H9(COO)3]2·6H2O·6CH3CN (2). The crystal structure of 2 indicates that each nickel(II) macrocyclic unit binds two CTC3 - ions in trans position and each CTC3 - ion coordinates three nickel(II) macrocyclic complexes to form a 2-D layer with hexagonal motif. The dried solid of 2 differentiates MeOH, EtOH, and PhOH in toluene solvent with the Kf values of 1.38, 2.11, and 6.68 M- 1, respectively.

AB - Abstract Reaction of the nickel(II) macrocyclic complex 1 including pendant pentyl groups in MeCN/H2O mixed solvent with deprotonated cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTC3 -) resulted in two-dimensional (2-D) coordination polymer [Ni(C18H42N6)]3[C6H9(COO)3]2·6H2O·6CH3CN (2). The crystal structure of 2 indicates that each nickel(II) macrocyclic unit binds two CTC3 - ions in trans position and each CTC3 - ion coordinates three nickel(II) macrocyclic complexes to form a 2-D layer with hexagonal motif. The dried solid of 2 differentiates MeOH, EtOH, and PhOH in toluene solvent with the Kf values of 1.38, 2.11, and 6.68 M- 1, respectively.

KW - Coordination polymer

KW - Crystal structure

KW - Guest binding

KW - Macrocyclic ligand

KW - Nickel(II)

UR - https://www.scopus.com/pages/publications/84928717895

U2 - 10.1016/j.inoche.2015.04.023

DO - 10.1016/j.inoche.2015.04.023

M3 - Article

AN - SCOPUS:84928717895

SN - 1387-7003

VL - 57

SP - 44

EP - 46

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 5977

ER -

Self-assembly and guest binding of nickel(II) macrocyclic complex with pentyl groups and cis,cis-1,3,5-cyclohexanetricarboxylic acid

Abstract

Keywords

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