TY - JOUR
T1 - Silicone-modified black peanut shell (BPS) biochar adsorbents
T2 - Preparation and their adsorptions for copper(II) from water
AU - Liu, Chen
AU - Yan, Xin
AU - Zhang, He Xin
AU - Yang, Jian ming
AU - Yoon, Keun Byoung
N1 - Publisher Copyright:
© 2024 The Author(s)
PY - 2024/8/15
Y1 - 2024/8/15
N2 - Novel silicone-modified biochar adsorbents (BPS-MBCs) were prepared by utilizing waste black peanut shell (BPS) as a raw biochar and gamma-amino-propyl triethoxysilane (silicone) as an inorganic modifier. The novelty of this work is that the incorporation of silicone into BPS can rise the specific surface area and porosity of BPS-MBCs and elevate their adsorptions for copper (II). Sorption kinetics data for copper (II) were molded using five kinetic equations [i.e. Lagergren 1st-order and 2nd-order, intraparticle diffusion (IN-D), Elovich, and Diffusion-chemisorption]. The equilibrium adsorption data for copper (II) were analyzed using two-parameter isotherm equations [i.e. Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin] and three-parameter Sips, Redlich-Peterson and Toth isotherm models. It was validated that copper (II) sorption on BPS-MBCs matched better with pseudo-2nd-order kinetic, Diffusion-chemisorption and Langmuir isotherm models. The maximal qmLan of BPS-MBC-400 was near 284 mg/g at 45 °C. By multi-phase fitting of IN-D modelling, intra-particle diffusion coefficient (kin-d) and diffusion coefficient of external mass-transfer (DEx-Di) for copper (II) were calculated. The low sorption energy from Temkin and mean free energy from D–R modellings implied that copper (II) sorption was initiated by weak non-covalent bond interactions. Thermodynamic parameters indicated that copper (II) on BPS-MBCs was an endothermic and spontaneous process. Recycling of BPS-MBC-400 for copper (II) suggested it has excellent reusability. The major mechanism of copper (II) on BPS-MBCs is possibly comprised of multiple processes, such as physical adsorption (electrostatic attraction), chemical adsorption (adsorption from functional groups, chelation, and ion exchange) and diffusion-chemisorption. Based on these findings, it is expects that BPS-MBCs are promising sorbents for copper (II) eradication from Cu(II)-including wastewater.
AB - Novel silicone-modified biochar adsorbents (BPS-MBCs) were prepared by utilizing waste black peanut shell (BPS) as a raw biochar and gamma-amino-propyl triethoxysilane (silicone) as an inorganic modifier. The novelty of this work is that the incorporation of silicone into BPS can rise the specific surface area and porosity of BPS-MBCs and elevate their adsorptions for copper (II). Sorption kinetics data for copper (II) were molded using five kinetic equations [i.e. Lagergren 1st-order and 2nd-order, intraparticle diffusion (IN-D), Elovich, and Diffusion-chemisorption]. The equilibrium adsorption data for copper (II) were analyzed using two-parameter isotherm equations [i.e. Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin] and three-parameter Sips, Redlich-Peterson and Toth isotherm models. It was validated that copper (II) sorption on BPS-MBCs matched better with pseudo-2nd-order kinetic, Diffusion-chemisorption and Langmuir isotherm models. The maximal qmLan of BPS-MBC-400 was near 284 mg/g at 45 °C. By multi-phase fitting of IN-D modelling, intra-particle diffusion coefficient (kin-d) and diffusion coefficient of external mass-transfer (DEx-Di) for copper (II) were calculated. The low sorption energy from Temkin and mean free energy from D–R modellings implied that copper (II) sorption was initiated by weak non-covalent bond interactions. Thermodynamic parameters indicated that copper (II) on BPS-MBCs was an endothermic and spontaneous process. Recycling of BPS-MBC-400 for copper (II) suggested it has excellent reusability. The major mechanism of copper (II) on BPS-MBCs is possibly comprised of multiple processes, such as physical adsorption (electrostatic attraction), chemical adsorption (adsorption from functional groups, chelation, and ion exchange) and diffusion-chemisorption. Based on these findings, it is expects that BPS-MBCs are promising sorbents for copper (II) eradication from Cu(II)-including wastewater.
KW - Adsorption
KW - Black peanut shell biochar
KW - Copper (II) adsorption
KW - Model
KW - Modified adsorbent
KW - Silicone
UR - http://www.scopus.com/inward/record.url?scp=85199952672&partnerID=8YFLogxK
U2 - 10.1016/j.heliyon.2024.e35169
DO - 10.1016/j.heliyon.2024.e35169
M3 - Article
AN - SCOPUS:85199952672
SN - 2405-8440
VL - 10
JO - Heliyon
JF - Heliyon
IS - 15
M1 - e35169
ER -