Single-crystalline hollow face-centered-cubic cobalt nanoparticles from solid face-centered-cubic cobalt oxide nanoparticles

Ki Min Nam, Jae Ha Shim, Hosung Ki, Sang Il Choi, Gaehang Lee, Jae Kwon Jang, Younghun Jo, Myung Hwa Jung, Hyunjoon Song, Joon T. Park

Research output: Contribution to journalArticlepeer-review

141 Scopus citations

Abstract

(Figure Presented) Hollow nan': Hollow face-centered cubic (fcc) Co nanoparallelepipeds were prepared by thermolysis of solid fcc CoO nanoparallelepipeds in oleylamine (see TEM image). The solid fcc CoO nanoparallelepipeds are reduced by the oleylamine surfactant to form hollow fcc Co nanoparallelepipeds. Voids and fcc Co are generated on the surface of the solid fcc CoO nanoparallelepipeds by the removal of oxide as carbon monoxide.

Original languageEnglish
Pages (from-to)9504-9508
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number49
DOIs
StatePublished - 24 Nov 2008

Keywords

  • Cobalt
  • Cobalt oxide
  • Hollow nanoparticles
  • Magnetic properties
  • Nanostructures

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