Solvent additive to achieve highly ordered nanostructural semicrystalline DPP copolymers: Toward a high charge carrier mobility

Tae Kyu An; Il Kang; Hui Jun Yun; Hyojung Cha; Jihun Hwang; Seonuk Park; Jiye Kim; Yu Jin Kim; Dae Sung Chung; Soon Ki Kwon; Yun Hi Kim; Chan Eon Park

doi:10.1002/adma.201301438

Solvent additive to achieve highly ordered nanostructural semicrystalline DPP copolymers: Toward a high charge carrier mobility

Tae Kyu An, Il Kang, Hui Jun Yun, Hyojung Cha, Jihun Hwang, Seonuk Park, Jiye Kim, Yu Jin Kim, Dae Sung Chung, Soon Ki Kwon, Yun Hi Kim, Chan Eon Park

Major in Hydrogen & Renewable Energy

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

A facile spin-coating method in which a small percentage of the solvent additive, 1-chloronaphthalene (CN), is found to increase the drying time during film deposition, is reported. The field-effect mobility of a PDPPDBTE film cast from a chloroform-CN mixed solution is 0.46 cm² V^-1 s ^-1. The addition of CN to the chloroform solution facilitates the formation of highly crystalline polymer structures.

Original language	English
Pages (from-to)	7003-7009
Number of pages	7
Journal	Advanced Materials
Volume	25
Issue number	48
DOIs	https://doi.org/10.1002/adma.201301438
State	Published - 23 Dec 2013

Keywords

additive effects
evaporation rates
high boiling points
organic field-effect transistors
spin-coating

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10.1002/adma.201301438

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title = "Solvent additive to achieve highly ordered nanostructural semicrystalline DPP copolymers: Toward a high charge carrier mobility",

abstract = "A facile spin-coating method in which a small percentage of the solvent additive, 1-chloronaphthalene (CN), is found to increase the drying time during film deposition, is reported. The field-effect mobility of a PDPPDBTE film cast from a chloroform-CN mixed solution is 0.46 cm2 V-1 s -1. The addition of CN to the chloroform solution facilitates the formation of highly crystalline polymer structures.",

keywords = "additive effects, evaporation rates, high boiling points, organic field-effect transistors, spin-coating",

author = "An, {Tae Kyu} and Il Kang and Yun, {Hui Jun} and Hyojung Cha and Jihun Hwang and Seonuk Park and Jiye Kim and Kim, {Yu Jin} and Chung, {Dae Sung} and Kwon, {Soon Ki} and Kim, {Yun Hi} and Park, {Chan Eon}",

year = "2013",

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doi = "10.1002/adma.201301438",

language = "English",

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TY - JOUR

T1 - Solvent additive to achieve highly ordered nanostructural semicrystalline DPP copolymers

T2 - Toward a high charge carrier mobility

AU - An, Tae Kyu

AU - Kang, Il

AU - Yun, Hui Jun

AU - Cha, Hyojung

AU - Hwang, Jihun

AU - Park, Seonuk

AU - Kim, Jiye

AU - Kim, Yu Jin

AU - Chung, Dae Sung

AU - Kwon, Soon Ki

AU - Kim, Yun Hi

AU - Park, Chan Eon

PY - 2013/12/23

Y1 - 2013/12/23

N2 - A facile spin-coating method in which a small percentage of the solvent additive, 1-chloronaphthalene (CN), is found to increase the drying time during film deposition, is reported. The field-effect mobility of a PDPPDBTE film cast from a chloroform-CN mixed solution is 0.46 cm2 V-1 s -1. The addition of CN to the chloroform solution facilitates the formation of highly crystalline polymer structures.

AB - A facile spin-coating method in which a small percentage of the solvent additive, 1-chloronaphthalene (CN), is found to increase the drying time during film deposition, is reported. The field-effect mobility of a PDPPDBTE film cast from a chloroform-CN mixed solution is 0.46 cm2 V-1 s -1. The addition of CN to the chloroform solution facilitates the formation of highly crystalline polymer structures.

KW - additive effects

KW - evaporation rates

KW - high boiling points

KW - organic field-effect transistors

KW - spin-coating

UR - http://www.scopus.com/inward/record.url?scp=84890807733&partnerID=8YFLogxK

U2 - 10.1002/adma.201301438

DO - 10.1002/adma.201301438

M3 - Article

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SN - 0935-9648

VL - 25

SP - 7003

EP - 7009

JO - Advanced Materials

JF - Advanced Materials

IS - 48

ER -

Solvent additive to achieve highly ordered nanostructural semicrystalline DPP copolymers: Toward a high charge carrier mobility

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Keywords

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